Pd{1,1'-bis(diphenylphosphino)ferrocene}I₂

Base Information

Chemical Name:Pd{1,1'-bis(diphenylphosphino)ferrocene}I₂
CAS No.:124268-94-6
Molecular Formula:C₃₄H₂₈FeI₂P₂Pd
Molecular Weight:914.62
Hs Code.:

Pd{1,1'-bis(diphenylphosphino)ferrocene}I<sub>2</sub>

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Chemical Property of Pd{1,1'-bis(diphenylphosphino)ferrocene}I₂

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Technology Process of Pd{1,1'-bis(diphenylphosphino)ferrocene}I₂

There total 2 articles about Pd{1,1'-bis(diphenylphosphino)ferrocene}I₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 12150-46-8
1,1'-bis-(diphenylphosphino)ferrocene

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: 7681-82-5,24359-64-6,41927-88-2,115813-40-6
sodium iodide

: 124268-94-6
Pd{1,1'-bis(diphenylphosphino)ferrocene}I₂

Guidance literature:: In acetone; to stirred suspn. of Fe-complex in acetone Pd-conplex was added, stirredfor 1 h, NaI was added, stirred for 30 min under inert atm.; concd. under reduced pressure, Et2O was added, filtered, washed with water, aq. EtOH, EtOH, Et2O;
DOI:10.1016/S0022-328X(01)00981-0

Reference yield: 65.0%

: 12150-46-8
1,1'-bis-(diphenylphosphino)ferrocene

: 7732-18-5
water

: 3375-31-3
palladium diacetate

: 124268-94-6
Pd{1,1'-bis(diphenylphosphino)ferrocene}I₂

: 32660-24-5
bis(2-(diphenylphosphoryl)cyclopenta-2,4-dien-1-yl)iron

: (diphenylphosphinoyl)ferrocene

: Ph₂PC₅H₄FeC₅H₄P(O)Ph₂

Guidance literature:: With sodium hydroxide; ethylene dibromide; sodium iodide; In dichloromethane; water; soln. NaOH and NaI in water was added to soln. dppfc, Pd(OAc)2, and 1,2-dibromoethane in CH2Cl2 and stirred under reflux (N2) for 23.5 h; organic layer was separated and evapd., residue was chromed. on silica; elem. anal.;
DOI:10.1021/om010454k

Reference yield:

: 124268-94-6
Pd{1,1'-bis(diphenylphosphino)ferrocene}I₂

: 119950-16-2
E-2`-bromo-4-methoxyphenyl-(2`-⁽¹³⁾C)ethene

: dilithio (cyclo-octatetraenide)

: 16750-63-3
2-methoxyphenylmagnesium bromide

: (1,1`-bis(diphenylphosphino)ferrocene)Pd(p-OMeC₆H₄CHCH)I

: (C₅H₄)2Fe(P(C₆H₅)2)2PdI(⁽¹³⁾CHCHC₆H₄OCH₃)

Guidance literature:: In tetrahydrofuran; Ar-atmosphere; addn. of LiCOT to Pd-complex (-78°C, stirring), addn. of (13)C-labeled alkene, addn. of further Pd-complex (-20°C), addn. of o-anisylmagnesium bromide (-20°C); not isolated, determined by NMR spectroscopy; various product ratio depending on labeling degree of educt;
DOI:10.1021/om00116a010