[Cp*Ir(η3-CH2CHCHPh)(NH=C(OMe)Me)]OTf

Base Information

• Chemical Name: [Cp*Ir(η3-CH2CHCHPh)(NH=C(OMe)Me)]OTf
• CAS No.: 260783-86-6
• Molecular Formula: CF₃O₃S*C₂₂H₃₁IrNO
• Molecular Weight: 666.785
• Mol file: 260783-86-6.mol

Synonyms:

Chemical Property of [Cp*Ir(η3-CH2CHCHPh)(NH=C(OMe)Me)]OTf

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Cp*Ir(η3-CH2CHCHPh)(NH=C(OMe)Me)]OTf

There total 6 articles about [Cp*Ir(η3-CH2CHCHPh)(NH=C(OMe)Me)]OTf which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

methanol (67-56-1) + [Cp(*)Ir(η(3)-CHPhCHCH2)(NCMe)](OTf) (191666-77-0) → [Cp*Ir(η3-CH2CHCHPh)(NH=C(OMe)Me)]OTf (260783-86-6,261158-77-4)

Guidance literature:

With Na₂CO₃; In methanol; methanol soln. (Cp*Ir(η3-CH2CHCHPh)(NCMe))OTf was refluxed in the presence of Na2CO3 for 6 h; react. mixt. was filtered, solvent was distilled off under vac., residuewas recrystd. from cold CHCl3/Et2O; elem. anal.;

DOI:10.1021/om9908480

Reference yield:

[Cp*Ir(η3-CH2CHCHPh)(NH=C(OMe)Me)]OTf (261158-77-4,260783-86-6) → [Cp*Ir(η3-CH2CHCHPh)(NH=C(OMe)Me)]OTf (260783-86-6,261158-77-4)

Guidance literature:

With Na₂CO₃; In chloroform; refluxing CHCl3 soln. of the complex in thepresence of Na2CO3;

DOI:10.1021/om9908480

Reference yield:

methanol (67-56-1) + [Cp*Ir(η3-CH2CHCHPh)(NH=C(OEt)Me)]OTf (261158-79-6,260783-88-8) → [Cp*Ir(η3-CH2CHCHPh)(NH=C(OMe)Me)]OTf (260783-86-6,261158-77-4)

Guidance literature:

With Na₂CO₃; In methanol; soln. of the complex in methanol was stirred at room temp. for 24 h in the presence of Na2CO3;

DOI:10.1021/om9908480

upstream raw materials:

[Cp*Ir(η3-CH2CHCHPh)(NH=C(OMe)Me)]OTf

methanol

[Cp(*)Ir(η(3)-CHPhCHCH2)(NCMe)](OTf)

[Cp*Ir(η3-CH2CHCHPh)(NH=C(OEt)Me)]OTf

Downstream raw materials:

methyl acetimidate

[Cp*Ir(η3-CH2CHCHPh)(PPh3)]OTf

[Cp*Ir(η3-CH2CHCHPh)(NH=C(OMe)Me)]OTf

Refernces