(η-Cp)Fe(CO){PPh2H}COMe

Base Information

Chemical Name:(η-Cp)Fe(CO){PPh2H}COMe
CAS No.:117227-88-0
Molecular Formula:C₂₀H₁₉FeO₂P
Molecular Weight:378.19
Hs Code.:

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Chemical Property of (η-Cp)Fe(CO){PPh2H}COMe

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Technology Process of (η-Cp)Fe(CO){PPh2H}COMe

There total 1 articles about (η-Cp)Fe(CO){PPh2H}COMe which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: dicarbonyl(cyclopentadienyl)methyliron(II)

: 829-85-6
diphenylphosphane

: 117227-88-0
(η-Cp)Fe(CO){PPh2H}COMe

Guidance literature:: In acetonitrile; refluxing a soln. of Fe-complex and PPh2H in MeCN for 17 h under Ar; removal of solvent, column chromy., elution with petroleum ether and then with CH2Cl2, orange band, elem. anal.;
DOI:10.1016/0022-328X(93)80360-N

Reference yield: 72.0%

: 117227-88-0
(η-Cp)Fe(CO){PPh2H}COMe

: 74-88-4
methyl iodide

: 117227-96-0
(η-Cp)Fe(CO){PMePh2}COMe

Guidance literature:: With n-BuLi; In tetrahydrofuran; cooling a soln. of Fe-complex in THF to -78°C, treating with n-BuLi under Ar, colour changes to dark red, stirring for 15 min, addn. of MeI; warming to room temp., removal of solvent, column chromy., elution with CH2Cl2, removal of solvent, recrystn. from petroleum ether, elem. anal.;
DOI:10.1016/0022-328X(93)80360-N

Reference yield: 62.0%

: 117227-88-0
(η-Cp)Fe(CO){PPh2H}COMe

: 922-67-8
propynoic acid methyl ester

: C₅H₅Fe(CO)(P(C₆H₅)2CHCHCO₂CH₃)(COCH₃)

: C₅H₅Fe(CO)(P(C₆H₅)2CHCHCO₂CH₃)(COCH₃)

Guidance literature:: With n-BuLi; In tetrahydrofuran; cooling a soln. of Fe-complex in THF to -78°C, treating with n-BuLi under Ar, stirring for 10 min, addn. of methyl propiolate, stirring for 20 min, addn. of acetic acid; warming to room temp., removal of solvent, column chromy., elution with CH2Cl2/acetone yields product mixt., elution (CH2Cl2/acetone), removal of solvent, trituration with Et2O, elem. anal.;
DOI:10.1016/0022-328X(93)80360-N