trans-[Pt(Ph)(OSiMe₂(C₆H₄CF₃-4))(PPh₃)2]

Base Information

• Chemical Name: trans-[Pt(Ph)(OSiMe₂(C₆H₄CF₃-4))(PPh₃)2]
• CAS No.: 364377-56-0
• Molecular Formula: C₅₁H₄₅F₃OP₂PtSi
• Molecular Weight: 1016.03
• Mol file: 364377-56-0.mol

Synonyms:

Chemical Property of trans-[Pt(Ph)(OSiMe₂(C₆H₄CF₃-4))(PPh₃)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[Pt(Ph)(OSiMe₂(C₆H₄CF₃-4))(PPh₃)2]

There total 1 articles about trans-[Pt(Ph)(OSiMe₂(C₆H₄CF₃-4))(PPh₃)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

trans-iodophenylbis(triphenylphosphine)platinum(II) + hydroxy(dimethyl)(4-trifluoromethylphenyl)silane (228873-97-0) → trans-[Pt(Ph)(OSiMe2(C6H4CF3-4))(PPh3)2] (364377-56-0)

Guidance literature:

With Ag₂O; In toluene; (N2 or Ar); Ag2O and then HOSiMe2C6H4CF3 added to Pt complex suspn., stirred for 24 h at room temp.; filtered, solid washed with toluene; the combined filtrate and washings evapd., washed (hexane), dried (vac.); elem. anal.;

DOI:10.1016/S0022-328X(01)00796-3

Reference yield:

trans-[Pt(Ph)(OSiMe2(C6H4CF3-4))(PPh3)2] (364377-56-0) + dichloromethane (75-09-2) → trans-Pt(phenyl)Cl(triphenylphosphine)2 (18421-49-3)

Guidance literature:

In hexane; dichloromethane; (N2 or Ar); recrystn.;

DOI:10.1016/S0022-328X(01)00796-3

Reference yield:

trans-[Pt(Ph)(OSiMe2(C6H4CF3-4))(PPh3)2] (364377-56-0) + chloroform-d1 (865-49-6) → trans-Pt(phenyl)Cl(triphenylphosphine)2 (18421-49-3)

Guidance literature:

In chloroform-d1; (N2 or Ar); dissolution at room temp.; not isolated, detected by NMR;

DOI:10.1016/S0022-328X(01)00796-3

upstream raw materials:

hydroxy(dimethyl)(4-trifluoromethylphenyl)silane

Downstream raw materials:

trans-Pt(phenyl)Cl(triphenylphosphine)2