TiCl₃(acetonitrile)3

Base Information

Chemical Name:TiCl₃(acetonitrile)3
CAS No.:37580-88-4
Molecular Formula:C₆H₉Cl₃N₃Ti
Molecular Weight:277.397
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of TiCl₃(acetonitrile)3

Chemical Property:

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Technology Process of TiCl₃(acetonitrile)3

There total 2 articles about TiCl₃(acetonitrile)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: tris-(triphenylphosphine)chloroplatinum(II) undecachlorotrititanate

: 75-05-8,26809-02-9
acetonitrile

: 71737-43-4
TiCl₄ * triphenylphosphine * acetonitrile

: 27183-96-6,18039-89-9,37580-88-4
TiCl₃(acetonitrile)3

Guidance literature:: In acetonitrile; condensation of excess MeCN onto Pt-complex (-78°C), warming to 25°C (stirring); filtration, pptn. on cyclopentane addn., filtration, volume reduction offiltrate, pptn. on cyclopentane addn.;
DOI:10.1016/S0020-1693(00)89370-6

Reference yield:

: 60-29-7,927820-24-4
diethyl ether

: 930-69-8
sodium thiophenolate

: 7550-45-0
titanium tetrachloride

: 75-05-8,26809-02-9
acetonitrile

: 27183-96-6,18039-89-9,37580-88-4
TiCl₃(acetonitrile)3

: 287957-78-2
Ti₃O(SC₆H₅)3Cl₄(CH₃CN)5*CH₃CN*(C₂H₅)2O

Guidance literature:: In acetonitrile; under N2, MeCN was added to NaSPh under stirring at room temp., TiCl4 was added, 2 h, 4 equiv. NaSPh was used relative to TiCl4; soln. was filtered, Et2O was added, soln. was left to stand at ambient temp., elem. anal.; total yield of Ti-compds.(they were formed ca. in 1:1 molar ratio) was ca. 70 % (based on Ti);
DOI:10.1016/S0277-5387(00)00374-0