I(C₆H₅)2Sn(CH₂)10Sn(C₆H₅)2I

Base Information

• Chemical Name: I(C₆H₅)2Sn(CH₂)10Sn(C₆H₅)2I
• CAS No.: 432028-31-4
• Molecular Formula: C₃₄H₄₀I₂Sn₂
• Molecular Weight: 939.921
• Mol file: 432028-31-4.mol

Synonyms:

Chemical Property of I(C₆H₅)2Sn(CH₂)10Sn(C₆H₅)2I

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of I(C₆H₅)2Sn(CH₂)10Sn(C₆H₅)2I

There total 1 articles about I(C₆H₅)2Sn(CH₂)10Sn(C₆H₅)2I which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,10-bis(triphenylstannyl)decane (87518-44-3) + iodine (7553-56-2,12190-71-5,8031-47-8) → I(C6H5)2Sn(CH2)10Sn(C6H5)2I (432028-31-4)

Guidance literature:

In chloroform; dropwise addn. of iodine in CHCl3 to a stirred soln. of Sn compd. in thesame solvent at 0°C, warming to room temp., stirrinng overnight; solvent removal in vac., phenyl iodide removal at 80°C and 1E-3 Torr for 2 h;

DOI:10.1039/b316009b

Reference yield:

I(C6H5)2Sn(CH2)10Sn(C6H5)2I (432028-31-4) + Chloromethyltrimethylsilane (2344-80-1) → (CH3)3SiCH2Sn(C6H5)2(CH2)10Sn(C6H5)2CH2Si(CH3)3 (432028-37-0)

Guidance literature:

With Mg; NH₄Cl; water; In tetrahydrofuran; adding Grignard soln. prepared from (CH3)3SiCH2Cl and Mg in THF to THF soln. of Sn compd., heating the mixt. under reflux overnight, cooling to room temp., treating with satd. NH4Cl, then with water; THF removal in vac., extn. (diethyl ether), drying the combined organic phases over Na2SO4, filtration, solvent removal in vac., volatiles removal at 80°C/1E-3 Torr;

DOI:10.1039/b316009b

upstream raw materials:

1,10-bis(triphenylstannyl)decane

iodine

Downstream raw materials:

(CH₃)3SiCH₂Sn(C₆H₅)2(CH₂)10Sn(C₆H₅)2CH₂Si(CH₃)3