1-chloro-2,2,3-trimethyl-3-phenyl-2-sila-3-germabutane

Base Information

• Chemical Name: 1-chloro-2,2,3-trimethyl-3-phenyl-2-sila-3-germabutane
• CAS No.: 119795-95-8
• Molecular Formula: C₁₁H₁₉ClGeSi
• Molecular Weight: 287.4
• Mol file: 119795-95-8.mol

Synonyms:

Chemical Property of 1-chloro-2,2,3-trimethyl-3-phenyl-2-sila-3-germabutane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 1-chloro-2,2,3-trimethyl-3-phenyl-2-sila-3-germabutane

There total 1 articles about 1-chloro-2,2,3-trimethyl-3-phenyl-2-sila-3-germabutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

dimethylphenylgermyllithium (25149-72-8) + Chloro(chloromethyl)dimethylsilane (1719-57-9) → 1-chloro-2,2,3-trimethyl-3-phenyl-2-sila-3-germabutane (119795-95-8) + 2,3,3,5-tetramethyl-2,5-diphenyl-3-sila-2,5-digermahexane (119796-01-9)

Guidance literature:

In tetrahydrofuran; hexane; adding soln. of (dimethylphenylgermyl)lithium in THF dropwise to soln. of chloro(chloromethyl)dimethylsilane in hexane/THF, stirring (5 min), quenching by addn. of satd. aq. NH4Cl; extg. (Et2O), washing extract (water, satd. aq. NaCl), drying (anhydrous MgSO4), concg. (reduced pressure), chromy. (silica gel, hexane);

DOI:10.1021/om00107a018

upstream raw materials:

dimethylphenylgermyllithium

Chloro(chloromethyl)dimethylsilane