Chloro(chloromethyl)dimethylsilane

Base Information

• Chemical Name: Chloro(chloromethyl)dimethylsilane
• CAS No.: 1719-57-9
• Molecular Formula: C3H8Cl2Si
• Molecular Weight: 143.088
• Hs Code.: 29310095
• European Community (EC) Number: 217-006-6
• DSSTox Substance ID: DTXSID4061911
• Nikkaji Number: J47.866K
• Wikidata: Q18211505
• Mol file: 1719-57-9.mol

Synonyms:Chloro(chloromethyl)dimethylsilane;1719-57-9;(Chloromethyl)dimethylchlorosilane;SILANE, CHLORO(CHLOROMETHYL)DIMETHYL-;CMDMCS;chloro-(chloromethyl)-dimethylsilane;CHLOROMETHYLDIMETHYLCHLOROSILANE;Chloro(cholromethyl)dimethylsilane;Dimethylchloromethylchlorosilane;EINECS 217-006-6;EC 217-006-6;(CH3)2SiCl(CH2Cl);PropranololBase;Chloro(chloromethyl)-dimethylsilane;CC3270;MFCD00000875;chlorochlormethyldimethylsilane;chlorochloromethyldimethylsilane;chloromethylchlorodimethylsilane;SCHEMBL124324;chloromethyldimethylsilyl chloride;DTXSID4061911;chloro-chloromethyl-dimethylsilane;chloromethyl-dimethyl-chlorosilane;ITKVLPYNJQOCPW-UHFFFAOYSA-;Chlorodimethyl(chloromethyl)silane;chloromethyl dimethylsilyl chloride;chloro-chloromethyl-dimethyl-silane;(chloromethyl)dimethylsilyl chloride;AKOS006221244;FS-4600;Chloro(chloromethyl)dimethylsilane, 98%;(Chloromethyl)Dimethylchlorosilane, 98%;(Chloromethyl)Dimethylchlorosilane, 98% 2;LS-192752;FT-0623680;I11126;J-520018;Q63408941;Chloro(chloromethyl)dimethylsilane, produced by Wacker Chemie AG, Burghausen, Germany, >=98.0% (GC)

Chemical Property of Chloro(chloromethyl)dimethylsilane

Chemical Property:

• Appearance/Colour: clear and colorless liquid
• Vapor Pressure: 25.6mmHg at 25°C
• Melting Point: < 0 °C
• Refractive Index: n20/D 1.437(lit.)
• Boiling Point: 112.5 °C at 760 mmHg
• Flash Point: 22.5 °C
• PSA: 0.00000
• Density: 1.047 g/cm³
• LogP: 2.62660
• Storage Temp.: Store below +30°C.
• Sensitive.: Moisture Sensitive
• Water Solubility.: DECOMPOSES
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 141.9772322
• Heavy Atom Count: 6
• Complexity: 44.1

Purity/Quality:

99% ^*data from raw suppliers

Chloro(chloromethyl)dimethylsilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C,F
• Hazard Codes: C,F
• Statements: 10-14-35-37-34-36/37-11
• Safety Statements: 26-36/37/39-45-25-16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[Si](C)(CCl)Cl
• Uses: Chloro(chloromethyl)dimethylsilane is an important intermediate for Alfa-series silane coupling agents, also can be used for synthesis of pesticides. Chloro(chloromethyl)dimethylsilane is used in method of improving the hydrophobic properties of cellulosic materials without leaving an acidic residue.

Technology Process of Chloro(chloromethyl)dimethylsilane

There total 17 articles about Chloro(chloromethyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

Chloromethyltrimethylsilane (2344-80-1) → Chloro(chloromethyl)dimethylsilane (1719-57-9) + sulfate de bis-(dimethylchloromethylsilyle) (20991-92-8) + methanesulfonyl chloride (124-63-0)

Guidance literature:

With chlorosulfonic acid; at 50 - 80 ℃;

Reference yield: 90.0%

chloro-trimethyl-silane (75-77-4) → Chloro(chloromethyl)dimethylsilane (1719-57-9)

Guidance literature:

With chlorine; for 17h; Heating; Irradiation;

Reference yield: 89.0%

1,3-Bis(chloromethyl)-1,1,3,3-tetramethyldisiloxane (2362-10-9) → Chloro(chloromethyl)dimethylsilane (1719-57-9) + 1,1,3,3-tetramethyl-1,3-bis(2-oxo-1-pyrrolidinomethyl)-1,3-disiloxane (82878-53-3)

Guidance literature:

With 1-(dimethylchlorosilylmethyl)pyrrolidin-2-one; for 1h; Heating;

upstream raw materials:

chloro-trimethyl-silane

Chloromethyltrimethylsilane

(dichloromethyl)trimethylsilane

octamethyltrisilane

Downstream raw materials:

chloromethyl(ethyl)dimethylsilane

chloromethyl(2-methylphenyl)dimethylchlorosilane

2,2,4,4,6,6,8,8,10,10,12,12-dodecamethyl-7-oxa-2,4,6,8,10,12-hexasila-tridecane

Chloromethyltrimethylsilane

Refernces

• 1、 Kornev, A. N.,Donnikova, O. S.,Semenov, V. V.,Kurskii, Yu. A.. "Synthesis of (trichloromethyl)organosilanes by catalytic decarboxylation of (trichloroacetoxy)organosilanes". . p. 145 - 148. Retrieved 2007/10/02.
• 2、 Chesnokova, T. A.,Kornev, A. N.,Semenov, V. V.,Kurskii, Yu. A.,Razuvaev, G. A.. "REACTIONS OF PERALKYLATED POLYSILANES WITH BENZOYL PEROXIDE". . p. 934 - 937. Retrieved 2007/10/02.