[(η5-C5Me5)Fe(1,3-bis(diphenylphosphino)propane)H]

Base Information

Chemical Name:[(η5-C5Me5)Fe(1,3-bis(diphenylphosphino)propane)H]
CAS No.:420796-88-9
Molecular Formula:C₃₇H₄₂FeP₂
Molecular Weight:604.535
Hs Code.:

Synonyms:

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Chemical Property of [(η5-C5Me5)Fe(1,3-bis(diphenylphosphino)propane)H]

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Technology Process of [(η5-C5Me5)Fe(1,3-bis(diphenylphosphino)propane)H]

There total 1 articles about [(η5-C5Me5)Fe(1,3-bis(diphenylphosphino)propane)H] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 16853-85-3
lithium aluminium tetrahydride

: 420796-84-5
[(η5-C5Me5)FeCl(1,3-bis(diphenylphosphino)propane)]*CH2Cl2

: 420796-88-9
[(η5-C5Me5)Fe(1,3-bis(diphenylphosphino)propane)H]

Guidance literature:: In tetrahydrofuran; LiAlH4 was added to THF soln. of complex at -80°C, the temp. was raised overnight (16 h) to 20°C, cooled to -80°C and CH3OHwas added dropwise, CH2Cl2 was added at room temp., stirred for 5 min ( inert atm.); the solvent was removed in vac., extd. with diethyl ether; elem. anal.;
DOI:10.1021/om0108245

Reference yield: 95.0%

: ferrocenium hexafluorophosphate

: 420796-88-9
[(η5-C5Me5)Fe(1,3-bis(diphenylphosphino)propane)H]

: 420796-93-6
[(η5C5Me5)FeH(1,3-bis(diphenylphosphino)propane)][PF6]

Guidance literature:: In tetrahydrofuran; (C5H5)2FEPF6 was added to THF soln. of complex at 20°C, stirred for 1 h (inert atm.); reduced in vol., pentane was added, ppt. was filtered, washed with diethyl ether, crystd. from THF-pentane; elem. anal.;
DOI:10.1021/om0108245

Reference yield: 82.0%

: 420796-88-9
[(η5-C5Me5)Fe(1,3-bis(diphenylphosphino)propane)H]

: 67-64-1
acetone

: 333-27-7
methyl trifluoromethanesulfonate

: [(η5-C5Me5)Fe(1,3-bis(diphenylphosphino)propane)][CF3SO3]*0.5CH3COCH3

Guidance literature:: In diethyl ether; CF3SO3CH3 was added to the soln. of complex in diethyl ether, the mixt. was stirred for 12 h at 20°C (inert atm.); filtered, ppt. was washed with pentane, disssolved in acetone, cold (-80°C) pentane was added, ppt. was filtered, washed with pentane, dried in vac,; elem. anal.;
DOI:10.1021/om0108245