4'-(4-pyridin-1-ylmethylphenyl)-[2,2':6',2'']-terpyridinehexafluorophosphate

Base Information

• Chemical Name: 4'-(4-pyridin-1-ylmethylphenyl)-[2,2':6',2'']-terpyridinehexafluorophosphate
• CAS No.: 865880-77-9
• Molecular Formula: C₂₇H₂₁N₄*F₆P
• Molecular Weight: 546.455
• Mol file: 865880-77-9.mol

Synonyms:

Chemical Property of 4'-(4-pyridin-1-ylmethylphenyl)-[2,2':6',2'']-terpyridinehexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4'-(4-pyridin-1-ylmethylphenyl)-[2,2':6',2'']-terpyridinehexafluorophosphate

There total 2 articles about 4'-(4-pyridin-1-ylmethylphenyl)-[2,2':6',2'']-terpyridinehexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pyridine (110-86-1) + 4'-(4-bromomethylphenyl)-2,2':6',2''-terpyridine (89972-78-1) → 4'-(4-pyridin-1-ylmethylphenyl)-[2,2':6',2'']-terpyridinehexafluorophosphate (865880-77-9)

Guidance literature:

pyridine; 4'-(4-bromomethylphenyl)-2,2':6',2''-terpyridine; at 150 ℃; for 0.5h; Microwave irradiation; Inert atmosphere; Schlenk technique;

With ammonium hexafluorophosphate; Inert atmosphere; Schlenk technique;

DOI:10.1039/c3cy00643c

Reference yield:

4'-(4-methylphenyl)-2,2':6',2-terpyridine (89972-77-0) → 4'-(4-pyridin-1-ylmethylphenyl)-[2,2':6',2'']-terpyridinehexafluorophosphate (865880-77-9)

Guidance literature:

Multi-step reaction with 2 steps

1.1: N-Bromosuccinimide / Inert atmosphere; Schlenk technique

2.1: 0.5 h / 150 °C / Microwave irradiation; Inert atmosphere; Schlenk technique

2.2: Inert atmosphere; Schlenk technique

With N-Bromosuccinimide;

DOI:10.1039/c3cy00643c

Reference yield: 70.0%

dichlorobis(dimethyl sulfoxide)platinum(II) + 4'-(4-pyridin-1-ylmethylphenyl)-[2,2':6',2'']-terpyridinehexafluorophosphate (865880-77-9) → [Pt(4'-(4-pyridin-1-ylmethylphenyl)-[2,2':6',2'']-terpyridine)Cl]PF6

Guidance literature:

In chloroform; under Ar; flask charged with ligand, Pt((CH3)2SO)2Cl2 and chloroform, heated at 50°C for 24 h; filtered, washed with cold EtOH, diethyl ether;

DOI:10.1021/ic050688m

upstream raw materials:

4'-(4-methylphenyl)-2,2':6',2-terpyridine

pyridine

4'-(4-bromomethylphenyl)-2,2':6',2''-terpyridine