mer-[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]ZrMe₂

Base Information

• Chemical Name: mer-[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]ZrMe₂
• CAS No.: 236111-38-9
• Molecular Formula: C₂₄H₃₇N₃Zr
• Molecular Weight: 458.802

Synonyms:

Chemical Property of mer-[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]ZrMe₂

Chemical Property:

Purity/Quality:

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Technology Process of mer-[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]ZrMe₂

There total 5 articles about mer-[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]ZrMe₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

methylmagnesium bromide (75-16-1) + zirconium(IV) chloride (10026-11-6) + (2,4,6-Me3C6H2NHCH2CH2)2NH (236111-35-6) → mer-[(2,4,6-Me3C6H2NCH2CH2)2NH]ZrMe2 (236111-38-9)

Guidance literature:

In diethyl ether; toluene; byproducts: MgClBr; under N2, amine was dissolved in toluene, ZrCl4 was added as a solid, heating at 80 °C and stirring for 24 h, cooling to room temp., 3.0 M MeMgBr was added in ether with stirring over 30 min, stirring for 60 min; MgClBr was filtered off, toluene and ether were removed in vac., solid was extd. with toluene, mixt. was filtered, soln. vol. was reduced, pentane was added, solid was filtered, washed with cold pentane, dried in vac., elem. anal.;

DOI:10.1021/om0004996

Reference yield: 76.0%

methyl magnesium iodide (917-64-6) + [(2,4,6-Me3C6H2NCH2CH2)2NH]ZrCl2 (236111-37-8,869331-91-9) → mer-[(2,4,6-Me3C6H2NCH2CH2)2NH]ZrMe2 (236111-38-9)

Guidance literature:

In diethyl ether; under N2, 3 M Et2O soln. of MeMgI was added to cold Et2O soln. of Zr-compd. (-30 °C), mixt. was warmed to room temp., stirring for 10 min; dioxane was added, ppt. was filtered off, filtrate was concd. in vac., pentane was added, pptn.;

DOI:10.1021/om0004996

Reference yield:

methyl magnesium iodide (917-64-6) + [((mesitylNCH2CH2)2NH)ZrCl2] → [((mesitylNCH2CH2)2NH)ZrMe2] (236111-38-9)

Guidance literature:

In diethyl ether; >2 equiv. of MeMgI;

DOI:10.1021/ja983636n

upstream raw materials:

methyl magnesium iodide

methylmagnesium bromide

zirconium(IV) chloride

(2,4,6-Me₃C₆H₂NHCH₂CH₂)2NH

Downstream raw materials:

[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NHZrMe(OEt₂)]B(C₆F₅)4

[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NHZrMe]B(C₆F₅)4

[((mesitylNCH₂CH₂)2NMe)ZrMe₂]

[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]Zr(⁽¹³⁾CH₃)2

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