1,2-dichlorotetramesityldigermane

Base Information

• Chemical Name: 1,2-dichlorotetramesityldigermane
• CAS No.: 100418-04-0
• Molecular Formula: C₃₆H₄₄Cl₂Ge₂
• Molecular Weight: 692.831
• Mol file: 100418-04-0.mol

Synonyms:

Chemical Property of 1,2-dichlorotetramesityldigermane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,2-dichlorotetramesityldigermane

There total 2 articles about 1,2-dichlorotetramesityldigermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

((CH3)3(C6H2))2GeHGeCl((CH3)3(C6H2))2 (100418-01-7) → 1,2-dichlorotetramesityldigermane (100418-04-0)

Guidance literature:

With tetrachloromethane; dibenzoyl peroxide; In tetrachloromethane; dry/inert atmosphere; refluxing (5 d); flash chromy. (silica gel, hexane/CH2Cl2);

DOI:10.1080/00945719608004362

Reference yield: 20.0%

tetrachloromethane (56-23-5) + tetrakis(2,4,6-trimethylphenyl)digermene (115385-07-4) → 1,2-dichlorotetramesityldigermane (100418-04-0)

Guidance literature:

In toluene; -40°C;

DOI:10.1139/V10-082

Reference yield: 76.0%

1,2-dichlorotetramesityldigermane (100418-04-0) + 3,5-di-tert-butyl-o-benzoquinone (3383-21-9) → dichlorodimesitylgermane (96481-42-4) + 2,2-dimesityl(6,8-di-t-butyl)-4,5-benzo-2-germa-1,3-dioxolane (110577-24-7)

Guidance literature:

In benzene-d6; Irradiation (UV/VIS); (high vacuum system), 4h at 30°C, 254 nm; detected by NMR, GC/MS;

DOI:10.1016/0022-328X(86)80434-X

upstream raw materials:

((CH₃)3(C₆H₂))2GeHGeCl((CH₃)3(C₆H₂))2

tetrachloromethane

tetrakis(2,4,6-trimethylphenyl)digermene

Downstream raw materials:

dichlorodimesitylgermane

2,2-dimesityl(6,8-di-t-butyl)-4,5-benzo-2-germa-1,3-dioxolane

hexamesitylcyclotrigermane

hexamesitylsiladigermirane