exo-5-hydroxy-2-norbornanone

Base Information

Chemical Name:exo-5-hydroxy-2-norbornanone
CAS No.:89898-02-2
Molecular Formula:C₇H₁₀O₂
Molecular Weight:126.155
Hs Code.:

Synonyms:

Suppliers and Price of exo-5-hydroxy-2-norbornanone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of exo-5-hydroxy-2-norbornanone

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of exo-5-hydroxy-2-norbornanone

There total 1 articles about exo-5-hydroxy-2-norbornanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 694-98-4
norborn-5-en-2-one

: 5745-61-9
hexahydro-cyclopenta[b]furan-2-one

: 5724-61-8
2-oxabicyclo[3.2.1]octan-3-one

: 58029-22-4,58029-23-5,89898-02-2,114529-14-5,114529-15-6
exo-5-hydroxy-2-norbornanone

Guidance literature:: With perchloric acid; water; at 85.1 ℃; Rate constant; Product distribution; hydration of 2-norbornen-5-one, disappearance rate constants for 2-norbornen-5-one and for some of its hydration products in HClO₄; mechanism of formation of the hydration products;

Reference yield: 87.0%

: 100-39-0
benzyl bromide

: 58029-22-4,58029-23-5,89898-02-2,114529-14-5,114529-15-6
5-endo-Hydroxybicyclo<2.2.1>heptan-2-one

: 110354-77-3,130014-67-4,136713-28-5,138124-94-4
5-endo-Benzyloxybicyclo<2.2.1>heptan-2-one

Guidance literature:: With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; In dichloromethane; for 20h; Heating;

Reference yield:

: 58029-22-4,58029-23-5,89898-02-2,114529-14-5,114529-15-6
5-endo-Hydroxybicyclo<2.2.1>heptan-2-one

: (1R,2S,5R,6R)-6-Methoxymethoxy-2-(3-methoxy-phenyl)-bicyclo[3.2.1]oct-3-en-2-ol

Guidance literature:: Multi-step reaction with 9 steps

1.1: Huenig base / CH₂Cl₂

2.1: LDA / tetrahydrofuran

3.1: Et₂Zn / CH₂Cl₂

4.1: FeCl₃

4.2: 86 percent / DBU

5.1: 91 percent / DIBAL / CH₂Cl₂

6.1: 98 percent / Et₃N; DMAP / CH₂Cl₂

7.1: 44 percent / Lipase PS / aq. phosphate buffer; acetone / 600 h

8.1: 96 percent / MnO₂ / CH₂Cl₂

9.1: 95 percent / nBuLi / tetrahydrofuran

With dmap; manganese(IV) oxide; n-butyllithium; Lipase PS; diethylzinc; iron(III) chloride; diisobutylaluminium hydride; triethylamine; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran; phosphate buffer; dichloromethane; acetone;
DOI:10.1021/ol015929i