2-Oxabicyclo[3.2.1]octan-3-one

Base Information

Chemical Name:2-Oxabicyclo[3.2.1]octan-3-one
CAS No.:5724-61-8
Molecular Formula:C7H10O2
Molecular Weight:126.155
Hs Code.:
DSSTox Substance ID:DTXSID00510255
Nikkaji Number:J604.359C

Synonyms:2-oxabicyclo[3.2.1]octan-3-one;5724-61-8;SCHEMBL4477475;oxabicyclo[3.2.1]octan-3-one;DTXSID00510255;JCYLVLDCMAUAKJ-UHFFFAOYSA-N;2-oxabicyclo[3.2.1]octan-3-on;EN300-175197

Suppliers and Price of 2-Oxabicyclo[3.2.1]octan-3-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 2-Oxabicyclo[3.2.1]octan-3-one

Chemical Property:

XLogP3:1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:126.068079557
Heavy Atom Count:9
Complexity:142

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2CC1CC(=O)O2

Technology Process of 2-Oxabicyclo[3.2.1]octan-3-one

There total 3 articles about 2-Oxabicyclo[3.2.1]octan-3-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 497-38-1
Norbornan-2-on

: 91-01-0
1,1-Diphenylmethanol

: 119-61-9
benzophenone

: 5724-61-8
2-oxabicyclo[3.2.1]octan-3-one

Guidance literature:: Norbornan-2-on; 1,1-Diphenylmethanol; With N-hydroxyphthalimide; 2,2'-azobis(isobutyronitrile); oxygen; In ethyl acetate; at 75 ℃; for 22h;

With ammonium cerium (IV) nitrate; 1,1,1,3',3',3'-hexafluoro-propanol; In ethyl acetate; at 45 ℃; for 10h;
DOI:10.1016/j.mcat.2020.110947

Reference yield:

: 694-98-4
norborn-5-en-2-one

: 5745-61-9
hexahydro-cyclopenta[b]furan-2-one

: 5724-61-8
2-oxabicyclo[3.2.1]octan-3-one

: 58029-22-4,58029-23-5,89898-02-2,114529-14-5,114529-15-6
exo-5-hydroxy-2-norbornanone

Guidance literature:: With perchloric acid; water; at 85.1 ℃; Rate constant; Product distribution; hydration of 2-norbornen-5-one, disappearance rate constants for 2-norbornen-5-one and for some of its hydration products in HClO₄; mechanism of formation of the hydration products;

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: (E)-7-Hydroxy-8-iodo-oct-2-enoic acid ethyl ester

: 5724-61-8
2-oxabicyclo[3.2.1]octan-3-one

: [3-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-acetic acid ethyl ester

: ((1R,3S)-3-Acetoxy-cyclopentyl)-acetic acid ethyl ester

Guidance literature:: With nickel(II) iodide; dmap; samarium; diiodomethane; triethylamine; Yield given. Multistep reaction. Yields of byproduct given; 1) THF, t-BuOH, -78 deg C, 30 min, -78 deg C --> rt; 2) CH2Cl2;
DOI:10.1021/jo971047e