di(4-trifluoromethylphenyl)tindichloride

Base Information

• Chemical Name: di(4-trifluoromethylphenyl)tindichloride
• CAS No.: 77459-83-7
• Molecular Formula: C₁₄H₈Cl₂F₆Sn
• Molecular Weight: 479.824
• Mol file: 77459-83-7.mol

Synonyms:

Chemical Property of di(4-trifluoromethylphenyl)tindichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of di(4-trifluoromethylphenyl)tindichloride

There total 1 articles about di(4-trifluoromethylphenyl)tindichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

p-trifluoromethylphenyl bromide (402-43-7) + tin(IV) chloride (7646-78-8) → di(4-trifluoromethylphenyl)tindichloride (77459-83-7)

Guidance literature:

at 180 ℃; for 120h;

DOI:10.1039/c8dt03043j

Reference yield: 99.0%

di(4-trifluoromethylphenyl)tindichloride (77459-83-7) + lithium dimethylamide (3585-33-9) → (p-CF3C6H4)2Sn(NMe2)2 (952516-13-1)

Guidance literature:

In benzene; under inert conditions, 1 equiv. of Sn-compd was added to an ice-cooled suspension of 2.2 equiv. of LiNMe2 in benzene, stirring at room temp. for 2 d; mixt. was filtered, volatiles were removed in vac.;

DOI:10.1016/j.poly.2007.06.002

Reference yield: 85.0%

4,4'-dimethyl-2,2'-bipyridines (1134-35-6) + di(4-trifluoromethylphenyl)tindichloride (77459-83-7) → cis-tin(IV)dichloride(4-trifluoromethylphenyl)(4,4'.dimethyl-2,2'-bipyridyl)

Guidance literature:

In toluene; Equimolar quantities of the starting materials in toluene are heated to boiling and mixed.; cooling to room temp., washing with light petroleum, vacuum drying, elem. anal.;

upstream raw materials:

p-trifluoromethylphenyl bromide

tin(IV) chloride

Downstream raw materials:

(p-CF₃C₆H₄)2Sn(NMe₂)2