dichlorotetrakis(N-phenyl-N'-(2-pyridyl)formamidinato)trinickel(II)*(dichloromethane)

Base Information

Chemical Name:dichlorotetrakis(N-phenyl-N'-(2-pyridyl)formamidinato)trinickel(II)*(dichloromethane)
CAS No.:622829-53-2
Molecular Formula:CH₂Cl₂*C₄₈H₄₀Cl₂N₁₂Ni₃
Molecular Weight:1116.83
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of dichlorotetrakis(N-phenyl-N'-(2-pyridyl)formamidinato)trinickel(II)*(dichloromethane)

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Technology Process of dichlorotetrakis(N-phenyl-N'-(2-pyridyl)formamidinato)trinickel(II)*(dichloromethane)

There total 1 articles about dichlorotetrakis(N-phenyl-N'-(2-pyridyl)formamidinato)trinickel(II)*(dichloromethane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

: 14076-99-4,20154-73-8,36829-43-3
[nickel(II)(pyridine)4(chloride)2]

: 75-09-2
dichloromethane

: 617690-51-4
N-phenyl-N'-(2-pyridyl)formamidine

: 622828-76-6
tetrakis(N-phenyl-N'-(2-pyridyl)formamidinato)dinickel

: 622829-53-2
dichlorotetrakis(N-phenyl-N'-(2-pyridyl)formamidinato)trinickel(II)*(dichloromethane)

Guidance literature:: With MeLi; In tetrahydrofuran; under N2; MeLi (1 equiv.) added to soln. of ligand in THF at -78°C; warmed to room temp.; added to Ni complex (2.25 equiv.); refluxed for15 h; filtered; vol. of filtrate reduced; ether added; filtered; solid washed with ether; dissolved in THF; hexanes added; filtered; solid dissolved in CH2Cl2; layered with hexanes; crystd. for 3 wk;
DOI:10.1016/S0020-1693(03)00112-9