bis(2-(azidomethyl)phenyl isocyanide)gold(I) tetrafluoroborate

Base Information

Chemical Name:bis(2-(azidomethyl)phenyl isocyanide)gold(I) tetrafluoroborate
CAS No.:690229-28-8
Molecular Formula:BF₄*C₁₆H₁₂AuN₈
Molecular Weight:600.096
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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(2-(azidomethyl)phenyl isocyanide)gold(I) tetrafluoroborate

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Technology Process of bis(2-(azidomethyl)phenyl isocyanide)gold(I) tetrafluoroborate

There total 1 articles about bis(2-(azidomethyl)phenyl isocyanide)gold(I) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.7%

: 14104-20-2
silver tetrafluoroborate

: 690229-26-6
chloro(2-(azidomethyl)phenyl isocyanide)gold(I)

: 496963-67-8
1-(azidomethyl)-2-isocyanobenzene

: 690229-28-8
bis(2-(azidomethyl)phenyl isocyanide)gold(I) tetrafluoroborate

Guidance literature:: In dichloromethane; acetone; byproducts: AgCl; under N2; acetone soln. of AgBF4 (1 equiv.) added under stirring at roomtemp. to soln. of Au complex in CH2Cl2; stirred for 10 min; filtered; f iltrate treated with ligand (1.1 equiv.); vol. reduced under reduced pressure; Et2O added; filtered; ppt. washed with Et2O; dried under vac.; elem. anal.;
DOI:10.1016/S0020-1693(03)00407-9

Reference yield: 88.2%

: 690229-28-8
bis(2-(azidomethyl)phenyl isocyanide)gold(I) tetrafluoroborate

: 603-35-0
triphenylphosphine

: 25749-32-0
bis(triphenylphosphine)gold(I) tetrafluoroborate

Guidance literature:: In dichloromethane; byproducts: 2-(azidomethyl)phenyl isocyanide; under N2; solid PPh3 (1.1 equiv.) added to soln. of Au complex in CH2Cl2; monitored by IR spectra; reacted for 30 min; second equiv. of PPh3 added; concd. to small vol.; treated with Et2O; filtered; ppt. washed with Et2O; dried under vac.; elem. anal.;
DOI:10.1016/S0020-1693(03)00407-9