Ru(η5-C5H2-2,4-(CO2Me)2-5-CH2CO2Me)Cl(CO)(PPh3)

Base Information

• Chemical Name: Ru(η5-C5H2-2,4-(CO2Me)2-5-CH2CO2Me)Cl(CO)(PPh3)
• CAS No.: 1095567-91-1
• Molecular Formula: C₃₁H₂₈ClO₇PRu
• Molecular Weight: 680.056
• Mol file: 1095567-91-1.mol

Synonyms:

Chemical Property of Ru(η5-C5H2-2,4-(CO2Me)2-5-CH2CO2Me)Cl(CO)(PPh3)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru(η5-C5H2-2,4-(CO2Me)2-5-CH2CO2Me)Cl(CO)(PPh3)

There total 2 articles about Ru(η5-C5H2-2,4-(CO2Me)2-5-CH2CO2Me)Cl(CO)(PPh3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

chloro-trimethyl-silane (75-77-4) + Ru(CHC(CO2CH3)CHC(CO2CH3)CCHC(OCH3)O)(CO)(P(C6H5)3)2 → Ru(η5-C5H2-2,4-(CO2Me)2-5-CH2CO2Me)Cl(CO)(PPh3) (1095567-91-1) + Ru(CHC(CO2CH3)CHC(CO2CH3)CCH2C(OCH3)O)Cl(P(C6H5)3)2

Guidance literature:

In benzene; Irradiation (UV/VIS); soln. of Ru complex and Me3SiCl in benzene-MeOH heated under reflux and irradiated with visible light for 2 h; more Me3SiCl added; heated and irradoiated for 2.5 h; solvent removed under reduced pressure; dissolved in min. of CH2Cl2-EtOH-Me3SiCl; sepd. by column chromy. (silica gel, CH2Cl2-EtOH-Me3SiCl 100:2:0.05); solvent removed;

DOI:10.1021/om800857k

Reference yield: 20.0%

hydrogenchloride (7647-01-0,15364-23-5) + Ru(CHC(CO2CH3)CHC(CO2CH3)CCHC(OCH3)O)(CO)(P(C6H5)3)2 → Ru(η5-C5H2-2,4-(CO2Me)2-5-CH2CO2Me)Cl(CO)(PPh3) (1095567-91-1) + Ru(CHC(CO2CH3)CHC(CO2CH3)CCH2C(OCH3)O)Cl(P(C6H5)3)2

Guidance literature:

In methanol; water; benzene; Ru complex and concd. aq. HCl heated under reflux in benzene-MeOH for 5 h; solvent removed under vac.; dissolved in CH2Cl2; small amt. of EtOH added; CH2Cl2 removed under reduced pressure; filtered; hexane (excess) added to filtrate; stored for 16 h; crystals collected by filtration; recrystd. from CH2Cl2-hexane; elem. anal.;

DOI:10.1021/om800857k

upstream raw materials:

chloro-trimethyl-silane

hydrogenchloride