[Fe(CO)4(2-oxazoline-2-ylmethyl)diphenylphosphine)]

Base Information

• Chemical Name: [Fe(CO)4(2-oxazoline-2-ylmethyl)diphenylphosphine)]
• CAS No.: 618883-94-6
• Molecular Formula: C₂₀H₁₆FeNO₅P
• Molecular Weight: 437.172
• Mol file: 618883-94-6.mol

Synonyms:

Chemical Property of [Fe(CO)4(2-oxazoline-2-ylmethyl)diphenylphosphine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe(CO)4(2-oxazoline-2-ylmethyl)diphenylphosphine)]

There total 1 articles about [Fe(CO)4(2-oxazoline-2-ylmethyl)diphenylphosphine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + 2-[(diphenylphosphanyl)-methyl]-4,5-dihydrooxazole (275377-93-0) → [Fe(CO)4(2-oxazoline-2-ylmethyl)diphenylphosphine)] (618883-94-6)

Guidance literature:

cobalt(II) chloride; In toluene; under N2; a toluene soln. of a ligand (10 mmol) and a catalytic amt. of anhyd. CoCl2 (0.385 mmol) were refluxed before Fe-contg. compd. (20 mmol) was added; reflux was continued until the IR spectrum remained invariant with time; cooling to room temp.; the mixt. was eluted with toluene through a column contg. CoCl2*6H2O/neutral alumina/silica gel; solvent and excess Fe(CO)5 were removed under reduced pressure; recrystn. from CH2Cl2-hexane; elem. anal.;

DOI:10.1039/b300277m

Reference yield: 80.0%

[Fe(CO)4(2-oxazoline-2-ylmethyl)diphenylphosphine)] (618883-94-6) + mercury(II) iodide → [((CO)4Fe(μ-(2-oxazoline-2-ylmethyl)diphenylphosphine-P,N))2HgI2] (618883-96-8)

Guidance literature:

In dichloromethane; under N2; dried HgI2 (0.30 mmol) was added to a CH2Cl2 soln. of Fe-contg. compd. (0.60 mmol) at room temp.; vigorous stirring; the soln. was concd. to half of its vol. under reduced pressure; overnight orange ppt. appeared; it was collected by filtration;

DOI:10.1039/b300277m

Reference yield: 77.0%

dichloromethane (75-09-2) + [Fe(CO)4(2-oxazoline-2-ylmethyl)diphenylphosphine)] (618883-94-6) + cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1) → [((CO)4Fe(μ-(2-oxazoline-2-ylmethyl)diphenylphosphine-P,N))2CoCl2]*1.5(dichloromethane)

Guidance literature:

In dichloromethane; under N2; dried CoCl2 (0.335 mmol) was added to a CH2Cl2 soln. of Fe-contg. compd. (0.667 mmol) at room temp.; vigorous stirring; the soln. was concd. to half of its vol. under reduced pressure; overnight blue crystals appeared; elem. anal.;

DOI:10.1039/b300277m

upstream raw materials:

iron pentacarbonyl

2-[(diphenylphosphanyl)-methyl]-4,5-dihydrooxazole

Downstream raw materials:

[((CO)4Fe(μ-(2-oxazoline-2-ylmethyl)diphenylphosphine-P,N))2HgI2]

[PdMeCl(κ2-P,N-(oxazolinylmethyl)diphenylphosphine)]