iron(III) methoxide tetrakispentafluorophenyl porphyrin

Base Information

• Chemical Name: iron(III) methoxide tetrakispentafluorophenyl porphyrin
• CAS No.: 854691-18-2
• Molecular Formula: C₄₅H₁₁F₂₀FeN₄O
• Molecular Weight: 1059.42
• Mol file: 854691-18-2.mol

Synonyms:

Chemical Property of iron(III) methoxide tetrakispentafluorophenyl porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of iron(III) methoxide tetrakispentafluorophenyl porphyrin

There total 2 articles about iron(III) methoxide tetrakispentafluorophenyl porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

(5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)iron(III) chloride (211934-69-9,36965-71-6) + sodium methylate (124-41-4) → iron(III) methoxide tetrakispentafluorophenyl porphyrin (854691-18-2)

Guidance literature:

In methanol; benzene; sodium methoxide in methanol was added to a soln. of complex in benzene-methanol, the soln. was stirred at room temp. for 1 h; reduced in vol. under vac., crystals were filtered, washed in methanol (0°C), dried at 44°C under 0.72 bar of vac.;

DOI:10.1021/ic0521067

Reference yield:

methanol (67-56-1) + (5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)iron(III) chloride (211934-69-9,36965-71-6) → iron(III) methoxide tetrakispentafluorophenyl porphyrin (854691-18-2)

Guidance literature:

In methanol; acetonitrile; CH3CN replaced with MeOH in soln. of iron porphyrin;

DOI:10.1021/ja043380n

upstream raw materials:

(5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)iron(III) chloride

sodium methylate

methanol