MeN(CHPhCH₂OH)(C₆H₄-o-OH)

Base Information

• Chemical Name: MeN(CHPhCH₂OH)(C₆H₄-o-OH)
• CAS No.: 1004984-50-2
• Molecular Formula: C₁₅H₁₇NO₂
• Molecular Weight: 243.305
• Mol file: 1004984-50-2.mol

Synonyms:

Chemical Property of MeN(CHPhCH₂OH)(C₆H₄-o-OH)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of MeN(CHPhCH₂OH)(C₆H₄-o-OH)

There total 1 articles about MeN(CHPhCH₂OH)(C₆H₄-o-OH) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

styrene oxide (96-09-3) + o-(N-methylamino)phenol (611-24-5) → MeN(CHPhCH2OH)(C6H4-o-OH) (1004984-50-2) + MeN(CH2CHPhOH)(C6H4-o-OH) (1004984-51-3)

Guidance literature:

at 90 ℃; for 34h; Title compound not separated from byproducts.;

DOI:10.1016/j.jorganchem.2007.10.020

Reference yield:

titanium(IV) isopropylate (546-68-9) + MeN(CHPhCH2OH)(C6H4-o-OH) (1004984-50-2) + MeN(CH2CHPhOH)(C6H4-o-OH) (1004984-51-3) → [MeN(CHPhCH2O)(C6H4-o-O)]2Ti (1004984-54-6) + [MeN(CH2CHPhO)(C6H4-o-O)]2Ti (1004984-55-7)

Guidance literature:

In toluene; under Ar atm. Ti(i-OPr)4 was added dropwise to soln. mixt. ligand in toluene and refluxed for 5 h; solvent was evapd. in vacuo, residue was crystd. from CH2Cl2-heptane (1:1), isomers were not separated; elem. anal.;

DOI:10.1016/j.jorganchem.2007.10.020

upstream raw materials:

styrene oxide

o-(N-methylamino)phenol

Downstream raw materials:

[MeN(CHPhCH₂O)(C₆H₄-o-O)]2Ti

[MeN(CH₂CHPhO)(C₆H₄-o-O)]2Ti