611-24-5

Basic information

• Product Name: 2-METHYLAMINOPHENOL
• Synonyms: 2-METHYLAMINOPHENOL;o-(methylamino)phenol;2-Methylaminophenol,97%;2-(Methylamino)phenol,N-Methyl-2-aminophenol, N-Methyl-2-hydroxyaniline;N-Methyl-2-hydroxyaniline;2-Hydroxy-N-methylaniline;N-Methyl-o-hydroxyaniline;NSC 245030
• CAS NO: 611-24-5
• Molecular Formula: C₇H₉NO
• Molecular Weight: 123.15
• EINECS: 210-263-5
• Mol File: 611-24-5.mol
• Article Data: 25

Chemical Properties

• Melting Point: 85-88 °C
• Boiling Point: 229.26°C (rough estimate)
• Flash Point: 122.1 °C
• Appearance: brown very fine crystalline powder
• Density: 1.0877 (rough estimate)
• Vapor Pressure: 0.0384mmHg at 25°C
• Refractive Index: 1.5730 (589.3 nm 33℃)
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• PKA: 10.62±0.10(Predicted)
• BRN: 970951
• CAS DataBase Reference: 2-METHYLAMINOPHENOL(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHYLAMINOPHENOL(611-24-5)
• EPA Substance Registry System: 2-METHYLAMINOPHENOL(611-24-5)

Safety Data

• Hazard Codes: Xn
• Statements: 22
• WGK Germany: 3
• Hazardous Substances Data: 611-24-5(Hazardous Substances Data)

Usage

Chemical Properties

brown very fine crystalline powder

InChI:InChI=1/C7H9NO/c1-8-6-4-2-3-5-7(6)9/h2-5,8-9H,1H3

Upstream product

• 6380-12-7 N-methyl-N-(2-methoxyphenyl)-4-methylbenzenesulfonamide 
• 21226-38-0 benzenesulfonic acid-(N-methyl-o-anisidide) 
• 95-55-6 2-amino-phenol 
• 74-88-4 methyl iodide 
• 2382-96-9 2-sulfanyl-1,3-benzoxazole 
• 7647-01-0 hydrogenchloride 
• 21892-80-8 3-methylbenzo[d]oxazol-2(3H)-one 
• 21744-84-3 4-methyl-4H-benzo[1,4]oxazin-3-one 
• 13673-63-7 3-methylbenzoxazole-2-thione 
• 573-27-3 2-(N-acetyl-N-methylamino)phenol 
• 468055-55-2 formic acid-(2-hydroxy-N-methyl-anilide) 
• 51301-44-1 3-Methylbenzoxazolium iodide 
• 616-38-6 carbonic acid dimethyl ester 
• 59-49-4 2-Benzoxazolinone 

Downstream Products

• 861295-38-7 2-(N-methylacetamido)phenyl acetate 
• 97025-73-5 2-(N-methyl-2,4-dinitro-anilino)-phenol 
• 832734-13-1 2-(2,4-dinitro-phenoxy)-N-methyl-aniline 
• 573-27-3 2-(N-acetyl-N-methylamino)phenol 
• 71038-59-0 N-Methyl-N-picryl-2-aminophenol 
• 87671-59-8 2,3-dihydro-2-methoxy-3-methyl-2,2-diphenyl-1,3,2-benzoxazaphosph(V)ole 
• 87671-60-1 2-ethoxy-2,3-dihydro-3-methyl-2,2-diphenyl-1,3,2-benzoxazaphosph(V)ole 
• 160893-30-1 4-chloro-2,3,5,6-tetrafluoro-2'-methylaminodiphenyl ether 
• 87671-62-3 2,3-dihydro-3-methyl-2-neopentoxy-2,2-diphenyl-1,3,2-benzoxazaphosph(V)ole 
• 87671-64-5 2-benzyloxy-2,3-dihydro-3-methyl-2,2-diphenyl-1,3,2-benzoxazaphosph(V)ole 
• 87271-56-5 2-(N-methylureido)phenol 
• 87671-65-6 2,3-dihydro-3-methyl-2-(4-methylbenzyloxy)-2,2-diphenyl-1,3,2-benzoxazaphosph(V)ole 
• 86509-80-0 2,3-dihydro-2-(2-methoxybenzyloxy)-3-methyl-2,2-diphenyl-1,3,2-benzoxazaphosph(V)ole 
• 344753-69-1 2-(2-ethoxybenzyloxy)-2,3-dihydro-3-methyl-2,2-diphenyl-1,3,2-benzoxazaphosph(V)ole 

Relevant articles and documents

PROCESS FOR MONO N-ALKYLATION OF AMINOPHENOL

The invention relates to a process for the preparation of a compound represented by formula (I) wherein X is selected from the group consisting of -H, -halogen, linear or branched C1-C7 alkyl group, linear or branched C1-C5 alkoxy group, - NO2

Method for sorting of pluripotent cells

A method for sorting pluripotent cells using a compound which is eliminated from the pluripotent cells through the MDR1 transporter.

Palladium-catalyzed ortho-acyloxylation of N-nitrosoanilines via direct sp2 C-H bond activation

The palladium-catalyzed N-nitroso-directed ortho-acyloxylation of N-nitrosoanilines has been demonstrated via sp2 C-H activation with a stoichiometric amount of PhI(OAc)2 as the oxidant and Ac2O/AcOH (1 : 1) or C2H5CO2H as the reaction medium. This protocol can be applied to various N-nitrosoanilines with both electron-donating and electron-withdrawing groups. In addition, the products can be further transformed to 2-(methylamino)phenols expediently by a simple reduction method.