dichlorobis(2-(ethylthiomethyl)phenyl)stannane

Base Information

• Chemical Name: dichlorobis(2-(ethylthiomethyl)phenyl)stannane
• CAS No.: 121114-62-3
• Molecular Formula: C₁₈H₂₂Cl₂S₂Sn
• Molecular Weight: 492.121
• Mol file: 121114-62-3.mol

Synonyms:

Chemical Property of dichlorobis(2-(ethylthiomethyl)phenyl)stannane

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of dichlorobis(2-(ethylthiomethyl)phenyl)stannane

There total 1 articles about dichlorobis(2-(ethylthiomethyl)phenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

2-<(ethylthio)methyl>bromobenzene (99180-11-7) + tin(IV) chloride (7646-78-8) → dichlorobis(2-(ethylthiomethyl)phenyl)stannane (121114-62-3)

Guidance literature:

With n-butyllithium; In diethyl ether; hexane; benzene; N2 atmosphere, addn. of BuLi in hexane to BrC6H4CH2SEt in ether (-30°C), warming to room temp., addn. of SnCl4 in benzene, reacting for 1 h; solvent evapn., recrystn. (CH2Cl2/hexane); elem. anal.;

DOI:10.1246/bcsj.61.1191

Reference yield: 79.0%

dichlorobis(2-(ethylthiomethyl)phenyl)stannane (121114-62-3) + tin(IV) chloride (7646-78-8) → trichloro(2-(ethylthiomethyl)phenyl)stannane (121114-63-4)

Guidance literature:

In toluene; N2 atmosphere, refluxing (12 h); solvent evapn., extraction (hexane), crystn. on cooling, recrystn. (CH2Cl2/hexane); elem. anal.;

DOI:10.1246/bcsj.61.1191

upstream raw materials:

2-<(ethylthio)methyl>bromobenzene

tin(IV) chloride

Downstream raw materials:

trichloro(2-(ethylthiomethyl)phenyl)stannane

Refernces