[(AuC2Ph)2(μ-4,4''-PPh2(C6H4)3PPh2)]

Base Information

• Chemical Name: [(AuC2Ph)2(μ-4,4''-PPh2(C6H4)3PPh2)]
• CAS No.: 1071768-67-6
• Molecular Formula: C₅₈H₄₂Au₂P₂
• Molecular Weight: 1194.85
• Mol file: 1071768-67-6.mol

Synonyms:

Chemical Property of [(AuC2Ph)2(μ-4,4''-PPh2(C6H4)3PPh2)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(AuC2Ph)2(μ-4,4''-PPh2(C6H4)3PPh2)]

There total 1 articles about [(AuC2Ph)2(μ-4,4''-PPh2(C6H4)3PPh2)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

gold(I) phenylacetylenide (34679-27-1) + 4,4'-bis(diphenylphosphino)-terphenyl (17249-04-6) → [(AuC2Ph)2(μ-4,4''-PPh2(C6H4)3PPh2)] (1071768-67-6)

Guidance literature:

In dichloromethane; toluene; to suspn. Au complex in CH2Cl2 ligand was added, diluted with toluene and stirred for 30 min in the absence of light; soln. was passed hrough alumina and concd., ppt. was centrifugated, washed with toluene and Et2O and vac.-dried;

DOI:10.1021/ic801073k

Reference yield: 61.0%

silver(I) hexafluorophosphate (26042-63-7) + silver(I) phenylacetylide (33440-88-9) + gold(I) phenylacetylenide (34679-27-1) + [(AuC2Ph)2(μ-4,4''-PPh2(C6H4)3PPh2)] (1071768-67-6) → [(Au10Ag12(C2Ph)20)Au3(PPh2(C6H4)3PPh2)3](PF6)5

Guidance literature:

In dichloromethane; acetone; Au complex was dissolved in CH2Cl2; soln. of AgPF6 in acetone was added;AuC2Ph and AgC2Ph were added; stirred for 2 h in absence of light; filtered; evapd.; recrystd. twice by diffusion of pentane into acetone soln.; elem. anal.;

DOI:10.1021/om8010036

Reference yield: 47.0%

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + [(AuC2Ph)2(μ-4,4''-PPh2(C6H4)3PPh2)] (1071768-67-6) → [(Cu12Au10(C2Ph)20)Au3(PPh2(C6H4)3PPh2)3][PF6]5

Guidance literature:

In dichloromethane; acetone; to soln. Au complex in CH2Cl2 soln. Cu complex in acetone was added dropwise, stirred for 30 min in the absence of light; hexane was added, solvents were removed in vacuo, residue was extd. withacetone-heptane (3:1) and evapd., recrystn. by pentane vapor diffusion in CH2Cl2 soln. at 5°C; elem. anal.;

DOI:10.1021/ic801073k

upstream raw materials:

gold(I) phenylacetylenide

4,4'-bis(diphenylphosphino)-terphenyl