C₆₁H₅₃BN₂Si

Base Information

• Chemical Name: C₆₁H₅₃BN₂Si
• CAS No.: 1404110-91-3
• Molecular Formula: C₆₁H₅₃BN₂Si
• Molecular Weight: 853.002
• Mol file: 1404110-91-3.mol

Synonyms:

Chemical Property of C₆₁H₅₃BN₂Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₁H₅₃BN₂Si

There total 4 articles about C₆₁H₅₃BN₂Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

p-(N-(2-(2'-pyridyl))indolyl)phenyl-p-(1-pyrenylphenyl)dimethylsilane (1404110-98-0) + dimesitylfluoroborane (436-59-9) → C61H53BN2Si (1404110-91-3)

Guidance literature:

p-(N-(2-(2'-pyridyl))indolyl)phenyl-p-(1-pyrenylphenyl)dimethylsilane; With n-butyllithium; In tetrahydrofuran; hexane; at -100 ℃; for 1h; Inert atmosphere;

dimesitylfluoroborane; In tetrahydrofuran; hexane; at -100 - 20 ℃; for 17h; Inert atmosphere;

DOI:10.1021/ol302742g

Reference yield:

bis(4-iodophenyl)dimethylsilane (146748-21-2) → C61H53BN2Si (1404110-91-3)

Guidance literature:

Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

1.2: 0.5 h / -78 °C / Inert atmosphere

1.3: 48.5 h / 0 - 20 °C / Inert atmosphere

2.1: potassium carbonate; copper(ll) sulfate pentahydrate / dodecane / 72 h / 220 °C / Inert atmosphere; Schlenk technique

3.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -100 °C / Inert atmosphere

3.2: 17 h / -100 - 20 °C / Inert atmosphere

With n-butyllithium; copper(ll) sulfate pentahydrate; potassium carbonate; In tetrahydrofuran; dodecane; hexane; 1.1: |Negishi Coupling / 1.2: |Negishi Coupling / 1.3: |Negishi Coupling / 2.1: |Ullmann Condensation;

DOI:10.1021/ol302742g

Reference yield:

1-bromopyrene (1714-29-0) → C61H53BN2Si (1404110-91-3)

Guidance literature:

Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

1.2: 0.5 h / -78 °C / Inert atmosphere

1.3: 48.5 h / 0 - 20 °C / Inert atmosphere

2.1: potassium carbonate; copper(ll) sulfate pentahydrate / dodecane / 72 h / 220 °C / Inert atmosphere; Schlenk technique

3.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -100 °C / Inert atmosphere

3.2: 17 h / -100 - 20 °C / Inert atmosphere

With n-butyllithium; copper(ll) sulfate pentahydrate; potassium carbonate; In tetrahydrofuran; dodecane; hexane; 1.1: |Negishi Coupling / 1.2: |Negishi Coupling / 1.3: |Negishi Coupling / 2.1: |Ullmann Condensation;

DOI:10.1021/ol302742g

upstream raw materials:

bis(4-iodophenyl)dimethylsilane

p-(N-(2-(2'-pyridyl))indolyl)phenyl-p-(1-pyrenylphenyl)dimethylsilane

dimesitylfluoroborane

1-bromopyrene