cis-dichloro(p-toluidine)(ethylene)platinum(II)

Base Information

• Chemical Name: cis-dichloro(p-toluidine)(ethylene)platinum(II)
• CAS No.: 12108-58-6
• Molecular Formula: C₉H₁₃Cl₂NPt
• Molecular Weight: 401.195
• Mol file: 12108-58-6.mol

Synonyms:

Chemical Property of cis-dichloro(p-toluidine)(ethylene)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-dichloro(p-toluidine)(ethylene)platinum(II)

There total 3 articles about cis-dichloro(p-toluidine)(ethylene)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium trichloro(ethene)platinate(II) (12012-50-9) + p-toluidine (106-49-0,12221-03-3) → {PtCl2} (12108-58-6,41766-93-2,40825-60-3)

Guidance literature:

With potassium hydroxide; In hydrogenchloride; water; soln. of p-toluidine in aq. HCl added to Zeie's salt in water; KOH added (pH 6);; ppt. crystd. from CH2Cl2/Et2O; elem. anal.;;

DOI:10.1016/0022-328X(84)80588-4

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + Zeise's dimer + p-toluidine (106-49-0,12221-03-3) → {PtCl2} (12108-58-6,41766-93-2,40825-60-3)

Guidance literature:

With sodium chloride; In water; dissolving of (Pt2(C2H4)2Cl4) at room temperature in an aq. soln. of NaCl; pptn. by addn. of p-toluidine in H2O and a small amount of HCl to the filtered, ice-cooled soln. with shaking; neutralization with NaOH;; rapid recrystallization in CCl4;;

Reference yield:

potassium tetrachloroplatinate(II) (10025-99-7) + ethene (74-85-1) + p-toluidine (106-49-0,12221-03-3) → cis-dichloro(p-toluidine)(ethylene)platinum(II) (40825-60-3,41766-93-2,12108-58-6)

Guidance literature:

In water; soln. of K2PtCl4 treated with p-toluidine; 5 d; 5°C; ppt. treated with aq. HCl; refluxed for 4 h with stirring; filtered; shaken with ethylene at 25°C and 40 p.s.i. pressure for 16 h;; ppt. recrystd. from acetone/Et2O; elem. anal.;;

DOI:10.1016/0022-328X(84)80588-4

upstream raw materials:

potassium trichloro(ethene)platinate(II)

p-toluidine

hydrogenchloride

potassium tetrachloroplatinate(II)

Downstream raw materials:

trans-dichloro(p-toluidine)(methyl allyl ether)platinum(II)

cis-dichloro(p-toluidine)(methyl allyl ether)platinum(II)

cis-dichloro(p-toluidine)(ethyl vinyl ether)platinum(II)

cis-dichloro(p-toluidine)(t-butyl vinyl ether)platinum(II)