Methyl 2-bromo-3,3-dimethoxypropanoate

Base Information

Chemical Name:Methyl 2-bromo-3,3-dimethoxypropanoate
CAS No.:191330-98-0
Molecular Formula:C₆H₁₁BrO₄
Molecular Weight:227.055
Hs Code.:
European Community (EC) Number:822-098-1

Synonyms:methyl 2-bromo-3,3-dimethoxypropanoate;191330-98-0;Propanoic acid, 2-bromo-3,3-dimethoxy-, methyl ester;SCHEMBL8816319;MFCD22392188;AKOS026730219;methyl2-bromo-3,3-dimethoxypropanoate;AS-76637;CS-0197831;D80663;EN300-112349

Suppliers and Price of Methyl 2-bromo-3,3-dimethoxypropanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Methyl 2-bromo-3,3-dimethoxypropanoate

Chemical Property:

XLogP3:0.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:225.98407
Heavy Atom Count:11
Complexity:124

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(C(C(=O)OC)Br)OC

Technology Process of Methyl 2-bromo-3,3-dimethoxypropanoate

There total 2 articles about Methyl 2-bromo-3,3-dimethoxypropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 67-56-1
methanol

: 5788-17-0
methyl (2E)-3-methoxy-2-propenoate

: 191330-98-0
2-Bromo-3,3-dimethoxy-propionic acid methyl ester

Guidance literature:: With N-Bromosuccinimide; at 5 - 20 ℃; for 16h;
DOI:10.1016/S0040-4039(98)00904-6

Reference yield: 82.0%

: 67-56-1
methanol

: 34846-90-7
methyl 3-methoxyprop-2-enoate

: 191330-98-0
2-Bromo-3,3-dimethoxy-propionic acid methyl ester

Guidance literature:: With N-Bromosuccinimide; at 5 - 20 ℃; Acidic conditions;
DOI:10.1021/tx100446g

Reference yield:

: 191330-98-0
2-Bromo-3,3-dimethoxy-propionic acid methyl ester

: 870106-30-2
7-(tert-butyl-diphenyl-silanyloxy)-2-dimethoxymethyl-4-ethoxythiocarbonylsulfanyl-heptanoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaI / diethyl ether / 1 h / 20 °C

1.2: diethyl ether / 18 h / 0 - 20 °C

2.1: 88 percent / dilauryl peroxide / 1,2-dichloro-ethane / 2 h / Heating

With dilauryl peroxide; sodium iodide; In diethyl ether; 1,2-dichloro-ethane;
DOI:10.1016/j.tetlet.2005.09.058