5788-17-0

Basic information

• Product Name: METHYL 3-METHOXYACRYLATE
• Synonyms: Methyl trans-3-methoxyacrylate,95%;Methyl 3-methoxyacrylate;(E)-Methyl 3-Methoxyacrylate;Methyl trans-3-Methoxyacrylate 97%;Methyl trans-3-methoxyacrylate;2-Propenoic acid,3-methoxy-, methyl ester, (2E)-;trans-3-methoxyacrylate;METHYL TRANS-3-METHOXYACRYLATE
• CAS NO: 5788-17-0
• Molecular Formula: C₅H₈O₃
• Molecular Weight: 116.12
• EINECS: 412-900-4
• Product Categories: C2 to C5;Carbonyl Compounds;Esters
• Mol File: 5788-17-0.mol
• Article Data: 5

Chemical Properties

• Melting Point: 3-4 °C
• Boiling Point: 56 °C18 mm Hg(lit.)
• Flash Point: 145 °F
• Appearance: /
• Density: 1.08 g/mL at 25 °C(lit.)
• Vapor Pressure: 3.05mmHg at 25°C
• Refractive Index: n20/D 1.451(lit.)
• Storage Temp.: 2-8°C
• CAS DataBase Reference: METHYL 3-METHOXYACRYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 3-METHOXYACRYLATE(5788-17-0)
• EPA Substance Registry System: METHYL 3-METHOXYACRYLATE(5788-17-0)

Safety Data

• Hazard Codes: Xi
• Statements: 43
• Safety Statements: 24-37
• RIDADR: UN 3334
• WGK Germany: 1
• Hazardous Substances Data: 5788-17-0(Hazardous Substances Data)

Usage

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Methyl trans-3-methoxyacrylate may be used in the preparation of:5- hydroxyquinolines7-hydroxyquinolinesmethyl 5-methoxyquinoline-3-carboxylate

InChI:InChI=1/C5H8O3/c1-7-4-3-5(6)8-2/h3-4H,1-2H3/b4-3+

Upstream product

• 67-56-1 methanol 
• 74783-15-6 C₁₀H₁₉O₈P 
• 292638-85-8 acrylic acid methyl ester 
• 124-41-4 sodium methylate 
• 184377-59-1 E-2-carbomethoxyethenyl p-tolyl sulfoxide 
• 74-88-4 methyl iodide 

Downstream Products

• 163041-47-2 (Z)-3-methoxy-2-iodo-acrylic acid methyl ester 
• 116406-21-4 (E)-3-(2,3,4-trimethoxy-phenyl)-acrylic acid methyl ester 
• 22027-50-5 methyl 3-(4-methoxybenzoyl)acetate 
• 1003944-25-9 N-(3-fluorophenyl)-3,3-bis(methyloxy)propanamide 
• 52867-35-3 1-methyl-3-hydroxy-1H-pyrazole 
• 33641-15-5 1-methyl-5-hydroxypyrazole 
• 325959-20-4 5-benzyl-4-methoxy-5H-furan-2-one 
• 852531-01-2 5-cyclohexylmethyl-4-methoxy-5H-furan-2-one 
• 1257108-95-4 4-methoxy-5-(phenylethyl)furan-2(5H)-one 
• 852531-99-8 4-methoxy-5-(3-phenyl-propyl)-5H-furan-2-one 
• 852532-49-1 4-methoxy-5-phenethyl-5-phenyl-5H-furan-2-one 
• 852532-39-9 5-[2-(4-benzyloxy-phenyl)ethyl]-4-methoxy-5H-furan-2-one 
• 164346-94-5 4-methoxy-5-methyl-5-phenethyl-5H-furan-2-one 
• 852471-15-9 1-(3-hydroxy-1H-pyrazol-1-yl)ethan-1-one 

Relevant articles and documents

Nucleophilic attack of 2-sulfinyl acrylates: A mild and general approach to sulfenic acid anions

An increasing number of reactions of sulfenic acid anions are being demonstrated in the literature. As such, mild, general and reliable means for the generation of sulfenates are due. In the current paper, an addition/elimination of 2-sulfinyl acrylates using various nucleophiles is demonstrated and evaluated as a protocol for alkane- and arenesulfenate generation. Cyclohexanethiolate, methoxide and n-butyllithum each exhibit some merit for the reaction, and the thiolate is established as a mild, selective and effective reagent to release sulfenates from 2-sulfinyl acrylates. The stereospecificity of the addition/elimination of each nucleophile is recognized, and an explanation for the specificity is offered for thiolate and methoxide.

β-Sulfinyl acrylate esters as a convenient source of alkane- and arenesulfenate anions

Methyl acrylate esters bearing alkane- and arenesulfinyl units on the 2-carbon liberate sulfenate anions upon nucleophilic attack. The sulfenates are readily captured through sulfur alkylation. When a sulfenate derived from R-cysteine is generated, diastereoselective benzylation is observed.

STABILITE THERMIQUE ET ALCOOLYSE DE QUELQUES YLURES DE TYPE

The thermal stability and alcoholysis reaction concerning ylides of the type X3P = is reported.These ylides undergo an addition reaction with methanol leading apparently to a pentacoordinated species which decomposes with or without breaking of the P-C bond.