cis-{rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)2}PF₆

Base Information

Chemical Name:cis-{rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)2}PF₆
CAS No.:113706-02-8
Molecular Formula:C₃₈H₃₆N₂P₂Rh*F₆P
Molecular Weight:830.534
Hs Code.:

cis-{rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)2}PF<sub>6</sub>

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Chemical Property of cis-{rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)2}PF₆

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Technology Process of cis-{rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)2}PF₆

There total 1 articles about cis-{rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)2}PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 26042-63-7
silver(I) hexafluorophosphate

: 12257-42-0
[(norbornadiene)rhodium(I)chloride]2

: 10150-27-3
2-(2-(diphenylphosphino)ethyl)pyridine

: 113706-02-8
cis-{rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)2}PF₆

Guidance literature:: In acetone; toluene; byproducts: AgCl; Under N2, a soln. of AgPF6 in acetone is added to a slurry of {Rh(nbd)Cl}2, a white AgCl ppt. forms, the mixt. is refluxed for 30 min and filtered, the yellow filtrate is added to excess PN in toluene.; The acetone is removed during reflux, a yellow ppt. forms which is filtered and washed with Et2O, recrystn. from CH2Cl2/Et2O, elem. anal.;

Reference yield: 66.0%

: 113706-02-8
cis-{rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)2}PF₆

: 201230-82-2
carbon monoxide

: 113706-04-0
{rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)2(CO)}PF₆

Guidance literature:: In tetrahydrofuran; Under N2, CO is bubbled through a suspn. of {Rh(PN)2}PF6 in THF until the mixt. becomes clear yellow (ca. 1 min), the soln. is stirred under CO atmosphere for addnl. 10 min.; Evapn. yields a glasslike residue, elem. anal.;