C₁₉H₃₀ClP

Base Information

• Chemical Name: C₁₉H₃₀ClP
• CAS No.: 100281-30-9
• Molecular Formula: C₁₉H₃₀ClP
• Molecular Weight: 324.874
• Mol file: 100281-30-9.mol

Synonyms:

Chemical Property of C₁₉H₃₀ClP

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₉H₃₀ClP

There total 9 articles about C₁₉H₃₀ClP which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

(Z)-2-(tert-butyldimethylsilyl)-2-chloro-1-(2,4,6-tri-tert-butylphenyl)-1-phosphaethene (1372610-09-7) → C19H30ClP (100281-30-9,92957-42-1,92957-44-3)

Guidance literature:

With tetramethylammonium fluoride; In tetrahydrofuran; for 24h; Inert atmosphere;

DOI:10.3998/ark.5550190.0013.203

Reference yield:

2,2-dichloro-1-(2,4,6-tri-tert-butylphenyl)-1-phosphaethene (100281-24-1) → E-2-chloro-1-(2,4,6-tri-t-butylphenyl)-1-phospha-ethylene (92957-42-1,92957-44-3,100281-30-9)

Guidance literature:

DOI:10.1080/10426509608545221

Reference yield:

chloroform (67-66-3,8013-54-5) → E-2-chloro-1-(2,4,6-tri-t-butylphenyl)-1-phospha-ethylene (92957-42-1,92957-44-3,100281-30-9)

Guidance literature:

In benzene; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;

DOI:10.1021/ja00153a013

upstream raw materials:

chloroform

2,4,6-tri-t-butylphenylphosphonous dichloride

C₁₉H₂₉ClLiP

Dichloromethyl-(2,4,6-tri-tert-butyl-phenyl)-phosphane

Downstream raw materials:

(E)-benzylidene(2,4,6-tri-tert-butylphenyl)phosphane

E-2-chloro-1-(2,4,6-tri-t-butylphenyl)-1-phospha-1-propene

2-(2,4,6-tri-tert-butylphenyl)phosphaacetylene

Refernces

• 1、 Van Der Sluis, Marcel,Wit, Jan B. M.,Bickelhaupt, Friedrich. "The synthetic potential of C-halophosphaalkenes". . p. 585 - 588. Retrieved 2007/10/03.
• 2、 Goede, Simon J.,Schaik, Henk P. van,Bickelhaupt, Friedrich. "SYNTHESIS AND REACTIVITY OF P-SUPERMESITYL-C-HALOPHOSPHAALKENES". . p. 252. Retrieved 2007/10/02.