[PdCl(1,3-bis(diphenylthiophosphinoyl)inden-2-yl)]*dichloromethane

Base Information

• Chemical Name: [PdCl(1,3-bis(diphenylthiophosphinoyl)inden-2-yl)]*dichloromethane
• CAS No.: 1333479-79-0
• Molecular Formula: CH₂Cl₂*C₃₃H₂₅ClP₂PdS₂
• Molecular Weight: 774.447
• Mol file: 1333479-79-0.mol

Synonyms:

Chemical Property of [PdCl(1,3-bis(diphenylthiophosphinoyl)inden-2-yl)]*dichloromethane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PdCl(1,3-bis(diphenylthiophosphinoyl)inden-2-yl)]*dichloromethane

There total 2 articles about [PdCl(1,3-bis(diphenylthiophosphinoyl)inden-2-yl)]*dichloromethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + dichloromethane (75-09-2) + 1,3-bis(diphenylthiophosphinoyl)indene (213266-62-7) → [PdCl(1,3-bis(diphenylthiophosphinoyl)inden-2-yl)]*dichloromethane (1333479-79-0)

Guidance literature:

In dichloromethane; (Ar, Schlenk technique); addn. of CH2Cl2 soln. of indene deriv. to CH2Cl2 soln. of palladium compd. at room temp., stirring for 2 hs; filtration, washing with CH2Cl2 and pentane, drying under vac., NMR;

DOI:10.1039/c1dt10118h

Reference yield:

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + dichloromethane (75-09-2) + [(2)H1]1,3-bis(diphenylphosphinoyl)indene (1333479-77-8) → [PdCl(1,3-bis(diphenylthiophosphinoyl)inden-2-yl)]*dichloromethane (1333479-79-0)

Guidance literature:

In tetrahydrofuran; (Ar, Schlenk technique); treatment of palladium compd. with indene deriv. in THF at room temp.;

DOI:10.1039/c1dt10118h

Reference yield: 63.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + [PdCl(1,3-bis(diphenylthiophosphinoyl)inden-2-yl)]*dichloromethane (1333479-79-0) + N-ethyl-N,N-diisopropylamine (7087-68-5) → [diisopropylethylammonium][PdCl(1,3-bis(diphenylthiophosphinoyl)inden-2-yl(2-))]*THF

Guidance literature:

In tetrahydrofuran; (Ar, Schlenk technique); addn. of amine deriv. to THF soln. of palladiumcompd. at -78°C, stirring for 2 hs at -78°C; addn. of pentane, filtration, drying under vac., NMR;

DOI:10.1039/c1dt10118h

upstream raw materials:

bis(benzonitrile)palladium(II) dichloride

dichloromethane

1,3-bis(diphenylthiophosphinoyl)indene

[⁽²⁾H₁]1,3-bis(diphenylphosphinoyl)indene