1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane bis(trifluoromethanesulfonyl)imide

Base Information

• Chemical Name: 1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane bis(trifluoromethanesulfonyl)imide
• CAS No.: 1465846-53-0
• Molecular Formula: C₂F₆NO₄S₂*C₂₀H₂₉N₂O₅S
• Molecular Weight: 689.675
• Mol file: 1465846-53-0.mol

Synonyms:

Chemical Property of 1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane bis(trifluoromethanesulfonyl)imide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane bis(trifluoromethanesulfonyl)imide

There total 6 articles about 1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane bis(trifluoromethanesulfonyl)imide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane iodide (1465846-47-2) + bis(trifluoromethane)sulfonimide lithium (90076-65-6) → 1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane bis(trifluoromethanesulfonyl)imide (1465846-53-0)

Guidance literature:

In water; acetone; at 40 ℃; for 24h; Inert atmosphere;

DOI:10.1039/c3cc45305g

Reference yield:

1,11-diiodo-3,6-9-trioxaundecane (36839-56-2) → 1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane bis(trifluoromethanesulfonyl)imide (1465846-53-0)

Guidance literature:

Multi-step reaction with 3 steps

1: caesium carbonate / acetone / 24 h / 45 °C

2: water / 48 h / 105 °C / Inert atmosphere

3: acetone; water / 24 h / 40 °C / Inert atmosphere

With caesium carbonate; In water; acetone;

DOI:10.1039/c3cc45305g

Reference yield:

2-(methylthio)benzoic acid (3724-10-5) → 1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane bis(trifluoromethanesulfonyl)imide (1465846-53-0)

Guidance literature:

Multi-step reaction with 3 steps

1: caesium carbonate / acetone / 24 h / 45 °C

2: water / 48 h / 105 °C / Inert atmosphere

3: acetone; water / 24 h / 40 °C / Inert atmosphere

With caesium carbonate; In water; acetone;

DOI:10.1039/c3cc45305g

upstream raw materials:

2-(methylthio)benzoic acid

1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane iodide

bis(trifluoromethane)sulfonimide lithium

Tetraethylene glycol