1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane iodide

Base Information

• Chemical Name: 1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane iodide
• CAS No.: 1465846-47-2
• Molecular Formula: C₂₀H₂₉N₂O₅S*I
• Molecular Weight: 536.431
• Mol file: 1465846-47-2.mol

Synonyms:

Chemical Property of 1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane iodide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane iodide

There total 6 articles about 1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

1-methyl-1H-imidazole (616-47-7) + 1-[2-(methylthio)benzoyloxy]-11-iodo-3,6,9-trioxaundecane (1465846-44-9) → 1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane iodide (1465846-47-2)

Guidance literature:

In water; at 105 ℃; for 48h; Inert atmosphere;

DOI:10.1039/c3cc45305g

Reference yield:

1,11-diiodo-3,6-9-trioxaundecane (36839-56-2) → 1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane iodide (1465846-47-2)

Guidance literature:

Multi-step reaction with 2 steps

1: caesium carbonate / acetone / 24 h / 45 °C

2: water / 48 h / 105 °C / Inert atmosphere

With caesium carbonate; In water; acetone;

DOI:10.1039/c3cc45305g

Reference yield:

2-(methylthio)benzoic acid (3724-10-5) → 1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane iodide (1465846-47-2)

Guidance literature:

Multi-step reaction with 2 steps

1: caesium carbonate / acetone / 24 h / 45 °C

2: water / 48 h / 105 °C / Inert atmosphere

With caesium carbonate; In water; acetone;

DOI:10.1039/c3cc45305g

upstream raw materials:

2-(methylthio)benzoic acid

1-methyl-1H-imidazole

1-[2-(methylthio)benzoyloxy]-11-iodo-3,6,9-trioxaundecane

Tetraethylene glycol

Downstream raw materials:

1-[2-(methylthio)benzoyloxy]-11-(3-methyl-1H-imidazolium-1-yl)-3,6,9-trioxaundecane bis(trifluoromethanesulfonyl)imide