1-mesityl-3-(4-pyridinylmethyl)imidazolium chloride

Base Information

• Chemical Name: 1-mesityl-3-(4-pyridinylmethyl)imidazolium chloride
• CAS No.: 1381801-43-9
• Molecular Formula: C₁₈H₂₀N₃*Cl
• Molecular Weight: 313.83
• Mol file: 1381801-43-9.mol

Synonyms:

Chemical Property of 1-mesityl-3-(4-pyridinylmethyl)imidazolium chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-mesityl-3-(4-pyridinylmethyl)imidazolium chloride

There total 1 articles about 1-mesityl-3-(4-pyridinylmethyl)imidazolium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

4-picolylchloride hydrochloride (1822-51-1) + N-(2,4,6-trimethylphenyl)imidazole (25364-44-7) → 1-mesityl-3-(4-pyridinylmethyl)imidazolium chloride (1381801-43-9)

Guidance literature:

With sodium hydrogencarbonate; In ethanol; for 18h; Reflux;

DOI:10.1039/c2dt30520h

Reference yield: 87.0%

dichloromethane (75-09-2) + 1-mesityl-3-(4-pyridinylmethyl)imidazolium chloride (1381801-43-9) + potassium carbonate (584-08-7) + palladium dichloride → bis[N-mesityl-N'-(4-pyridylmethyl)imidazol-2-ylidene] palladium(II) carbonate * CH2Cl2

Guidance literature:

In pyridine; (N2) suspn. imidazolium salt, K2CO3 and PdCl2 in pyridine was heated at 60°C for 5 days; react. mixt. was allowed to cool, solvent was removed in vacuo, residue was dissolced in CH2Cl2, washed with water and dried in vacuo, residue was recrystd. from CH2Cl2-Et2O (3:1) at 25°C;

DOI:10.1039/c2dt30520h

Reference yield: 72.0%

1-mesityl-3-(4-pyridinylmethyl)imidazolium chloride (1381801-43-9) + silver(l) oxide (20667-12-3) → [N-mesityl-N'-(4-pyridylmethyl)imidazol-2-ylidene] silverchloride

Guidance literature:

In dichloromethane; (N2) Ag2O in CH2Cl2 was added to soln. imidazolium salt at room temp., stirred for 4 h; soln. was filtered and evapd. in vacuo, residue was washed with Et2O; elem. anal.;

DOI:10.1039/c2dt30520h

upstream raw materials:

4-picolylchloride hydrochloride

N-(2,4,6-trimethylphenyl)imidazole