HRh(CO)(P(C₆H₄-4-CF₃)3)3

Base Information

Chemical Name:HRh(CO)(P(C₆H₄-4-CF₃)3)3
CAS No.:226957-34-2
Molecular Formula:C₆₄H₃₇F₂₇OP₃Rh
Molecular Weight:1530.78
Hs Code.:

HRh(CO)(P(C<sub>6</sub>H<sub>4</sub>-4-CF<sub>3</sub>)3)3

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Chemical Property of HRh(CO)(P(C₆H₄-4-CF₃)3)3

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Technology Process of HRh(CO)(P(C₆H₄-4-CF₃)3)3

There total 3 articles about HRh(CO)(P(C₆H₄-4-CF₃)3)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: acetylacetonatodicarbonylrhodium(l)

: 13406-29-6
tris(para-trifluoromethyl)phenyl phosphine

: 226957-34-2
HRh(CO)(P(C₆H₄-4-CF₃)3)3

Guidance literature:: With carbon monoxide; hydrogen; In further solvent(s); High Pressure; reactor with Rh(CO)2(acac) and phosphine (3 equiv.) was charged with H2/CO (2 equiv.), pressured with CO2 (205 atm) and stirred for 15 min;
DOI:10.1021/om990560a

Reference yield:

: acetylacetonatodicarbonylrhodium(l)

: 201230-82-2
carbon monoxide

: 1333-74-0
hydrogen

: 13406-29-6
tris(para-trifluoromethyl)phenyl phosphine

: 114835-23-3
HRh(CO)2((CF₃C₆H₄)3P)2

: 226957-34-2
HRh(CO)((CF₃C₆H₄)3P)3

Guidance literature:: In carbon dioxide; High Pressure; cell charged with Rh complex and ligand precursor and evacuated; addn. of H2 and CO (1:1) followed by adjusting the total pressure to 223 bar with CO2; soln. diffusionally mixed and reacted at 40 °C; not isolated; detected by high-pressure NMR;
DOI:10.1016/S0022-328X(02)01217-2

Reference yield:

: acetylacetonatodicarbonylrhodium(l)

: 201230-82-2
carbon monoxide

: 1333-74-0
hydrogen

: 13406-29-6
tris(para-trifluoromethyl)phenyl phosphine

: 226957-34-2
HRh(CO)((CF₃C₆H₄)3P)3

Guidance literature:: In carbon dioxide; byproducts: acetylacetone, (p-CF3C6H4)3PO; High Pressure; cell charged with Rh complex and ligand precursor and evacuated; addn. of .apprx.25 bar of H2-CO (1:1) followed by adjusting the total pressure to 207 bar with CO2; soln. diffusionally mixed and reacted at 50 °C for .apprx. 60 min; sample cooled and depressurized; volotiles removed by evacuation of sample overnight; detected by high-pressure NMR;
DOI:10.1016/S0022-328X(02)01217-2