trans-Pd₂I₄(PEt₃)2

Base Information

Chemical Name:trans-Pd₂I₄(PEt₃)2
CAS No.:69460-34-0
Molecular Formula:C₁₂H₃₀I₄P₂Pd₂
Molecular Weight:956.776
Hs Code.:

trans-Pd<sub>2</sub>I<sub>4</sub>(PEt<sub>3</sub>)2

Synonyms:

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Chemical Property of trans-Pd₂I₄(PEt₃)2

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Technology Process of trans-Pd₂I₄(PEt₃)2

There total 6 articles about trans-Pd₂I₄(PEt₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: ammonium hexafluorophosphate

: 30184-37-3,15638-56-9
trans-diiodobis(triethylphosphine)palladium(II)

: (palladium)10(carbonyl)12(triethylphosphine)6

: 3375-31-3
palladium diacetate

: Pd⁽²⁺⁾*2OC(O)CH₃^(1-)*2P(C₂H₅)3=Pd(OC(O)CH₃)2(P(C₂H₅)3)2

: 850331-68-9,69460-34-0,22180-56-9
trans-Pd₂I₄(PEt₃)2

: [Pd12(μ3-I)2(μ4-I)3(μ2-CO)6(PEt3)6][PF6]

: 7440-05-3
palladium

Guidance literature:: In tetrahydrofuran; byproducts: carbonmonoxide, ammonium iodide; (N2); mixture of Pd10(CO)12(PEt3)6, PdI2(PEt3)2, Pd(OAc)2, and NH4PF6 stirred for 3 h; evapn. of solvent via N2 flow, extn. with Et2O, washed with water, driedin vac., extn. with THF, addn. of hexane, crystn. overnight at -20 .deg ree.C;
DOI:10.1016/j.ica.2004.09.064

Reference yield: 17.0%

: ammonium hexafluorophosphate

: 30184-37-3,15638-56-9
trans-diiodobis(triethylphosphine)palladium(II)

: (palladium)10(carbonyl)12(triethylphosphine)6

: 850331-68-9,69460-34-0,22180-56-9
trans-Pd₂I₄(PEt₃)2

: [Pd12(μ3-I)2(μ4-I)3(μ2-CO)6(PEt3)6][PF6]

: 7440-05-3
palladium

Guidance literature:: In tetrahydrofuran; (N2); mixt. of Pd10(CO)12(PEt3)6, PdI2(PEt3)2, and NH4PF6 stirred in THFfor 1 d; evapn. of solvent via N2 flow, extn. with Et2O, washed with water, driedin vac, extn. with THF, addn. of hexane, crystn. overnight at -20 .degr ee.C;
DOI:10.1016/j.ica.2004.09.064

Reference yield: 8.0%

: [Pd₁₂Tl₂(CO)9(PEt₃)9][PF₆]2

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 30184-37-3,15638-56-9
trans-diiodobis(triethylphosphine)palladium(II)

: 850331-68-9,69460-34-0,22180-56-9
trans-Pd₂I₄(PEt₃)2

: [Pd12(μ3-I)2(μ4-I)3(μ2-CO)6(PEt3)6][PF6]

: 7440-05-3
palladium

Guidance literature:: In tetrahydrofuran; (N2); atm. soln. I2 in THF was added dropwise to soln. (Tl2Pd12(CO)9(PEt3)9)(PF6)2 in THF and stirred for 1 h, I2 was added and stirred for 2 h; soln. was filtered, crystn. from THF soln. in the presence of hexane;
DOI:10.1016/j.ica.2004.09.064