N-dimethylsulphilimine

Base Information

• Chemical Name: N-dimethylsulphilimine
• CAS No.: 84718-93-4
• Molecular Formula: C₁₂H₂₀NOPS
• Molecular Weight: 257.337
• Mol file: 84718-93-4.mol

Synonyms:

Chemical Property of N-dimethylsulphilimine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-dimethylsulphilimine

There total 6 articles about N-dimethylsulphilimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

(+/-)-P-t-butyl-P-phenyl-N-phosphoramidate (51028-18-3) + dimethyl sulfoxide (67-68-5,8070-53-9) → N-dimethylsulphilimine (84718-93-4)

Guidance literature:

With trifluoroacetic anhydride; In dichloromethane; 1.) -50 deg C, 1 h, 2.) room temperature, 2 h;

Reference yield: 32.0%

dimethylsulfide (75-18-3) + t-butyl(phenyl)phosphinic azide (84718-90-1) → (+/-)-P-t-butyl-P-phenyl-N-phosphoramidate (51028-18-3) + N-dimethylsulphilimine (84718-93-4) + N-(methylthiomethyl)-t-butyl(phenyl)phosphinic amide (84718-94-5)

Guidance literature:

for 8h; Irradiation;

Reference yield: 21.0%

t-butyl(phenyl)phosphinic azide (84718-90-1) → (+/-)-P-t-butyl-P-phenyl-N-phosphoramidate (51028-18-3) + N-dimethylsulphilimine (84718-93-4) + N-(methylthiomethyl)-t-butyl(phenyl)phosphinic amide (84718-94-5)

Guidance literature:

With dimethylsulfide; for 8h; Irradiation;

upstream raw materials:

methanol

t-butyl(phenyl)phosphinic azide

dimethylsulfide

(+/-)-P-t-butyl-P-phenyl-N-phosphoramidate