pyridine gallium chloride adduct

Base Information

• Chemical Name: pyridine gallium chloride adduct
• CAS No.: 856588-85-7
• Molecular Formula: C₅H₅Cl₃GaN
• Molecular Weight: 255.183
• Mol file: 856588-85-7.mol

Synonyms:

Chemical Property of pyridine gallium chloride adduct

Chemical Property:

Purity/Quality:

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Technology Process of pyridine gallium chloride adduct

There total 1 articles about pyridine gallium chloride adduct which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

decamethylsilicocene + Gallium trichloride (13450-90-3) → gallium (7440-55-3) + gallium trichloride-pyridine (1/1) (856588-85-7,15024-93-8)

Guidance literature:

In toluene; inert atmosphere; soln. of Si-compd. cooled to -80°C, addn. of GaCl3 (equiv. amt.) soln., warming to room temp., Gallium pptn. on standing (3-5 d), filtration of Ga, pptn. on pyridine addn. to filtrate; filtration;

DOI:10.1021/om9906114

Reference yield: 73.0%

pyridine gallium chloride adduct (15024-93-8,856588-85-7) + (O(CH2CH2PCy2)2)RuCl2(CHPh)*CH2Cl2 → [(O(CH2CH2PCy2)2)Ru(py)Cl(CHPh)][GaCl4]

Guidance literature:

In dichloromethane; (N2) to soln. Ru complex in CH2Cl2 soln. GaCl3*py in CH2Cl2 was added, stirred for 12 h; soln. was evapd. to dryness, residue was washed with hexane, dried in vacuo, taken up in CH2Cl2 and layered with hexane; elem. anal.;

DOI:10.1021/om100707a

upstream raw materials:

Gallium trichloride