((η5-C5Me5)Ru(μ-hydrido))2(μ-phenylmethylsilylene)(μ-dimethylsylylene)

Base Information

Chemical Name:((η5-C5Me5)Ru(μ-hydrido))2(μ-phenylmethylsilylene)(μ-dimethylsylylene)
CAS No.:610798-45-3
Molecular Formula:C₂₉H₄₆Ru₂Si₂
Molecular Weight:652.995
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ((η5-C5Me5)Ru(μ-hydrido))2(μ-phenylmethylsilylene)(μ-dimethylsylylene)

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Technology Process of ((η5-C5Me5)Ru(μ-hydrido))2(μ-phenylmethylsilylene)(μ-dimethylsylylene)

There total 1 articles about ((η5-C5Me5)Ru(μ-hydrido))2(μ-phenylmethylsilylene)(μ-dimethylsylylene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: tetra-μ-hydrido-bis[(pentamethyl-η5-cyclopentadienyl)ruthenium]

: 766-77-8
Dimethylphenylsilane

: 610798-46-4
((η5-C5Me5)Ru(μ-dimethylsilylene)(μ-hydrido))2

: ((η5-C5Me5)Ru(μ-η2-dimethylsilyl))2(μ-hydrido)(hydrido)

: 610798-45-3
((η5-C5Me5)Ru(μ-hydrido))2(μ-phenylmethylsilylene)(μ-dimethylsylylene)

: 610798-82-8
((η5-C5Me5)Ru)2(μ-η2-phenylmethylsilyl)(μ-η2-dimethylsylyl)(μ-hydrido)(hydrido)

Guidance literature:: In toluene; byproducts: dihydrogen; under Ar; 2.5 molar equiv of PhMe2SiH added with vigorous stirring to Cp*Ru(μ-H)4RuCp* in toluene at -78 °C; soln. allowed to react for 2 h at 0 °C with Ar bubbling; solvent and silane removed under reduced pressure; anal. pure major product obtained by recrystn. from cold pentane soln.; elem. anal.;
DOI:10.1021/om030429+

Reference yield: 80.0%

: 610798-45-3
((η5-C5Me5)Ru(μ-hydrido))2(μ-phenylmethylsilylene)(μ-dimethylsylylene)

: 1333-74-0
hydrogen

: 610798-82-8
((η5-C5Me5)Ru)2(μ-η2-phenylmethylsilyl)(μ-η2-dimethylsylyl)(μ-hydrido)(hydrido)

Guidance literature:: In toluene; under Ar; toluene and crude (Cp*Ru(μ-H))2(μ-SiMe2)(μ-SiPhMe) charged in react. flask and degassed; 1 atm of H2 introduced; soln. vigorously stirred for 2 h at 25 °C; solvent removed under reduced pressure; isolation by column chromy. failed due to decompn. on alumina; NMR spectroscopy;
DOI:10.1021/om030429+

Reference yield: 37.0%

: 610798-45-3
((η5-C5Me5)Ru(μ-hydrido))2(μ-phenylmethylsilylene)(μ-dimethylsylylene)

: 201230-82-2
carbon monoxide

: 93060-48-1,70669-56-6,856900-13-5
[Ru(CO)2(η5-1,2,3,4,5-pentamethylcyclopentadienyl)]

: 610798-63-5
trans-((η5-C5Me5)Ru(carbonyl))2(μ-phenylmethylsilylene)(μ-dimethylsylylene)

Guidance literature:: In toluene; High Pressure; under Ar; toluene and (Cp*Ru(μ-H))2(μ-SiPhMe)(μ-SiMe2) charged in glass autoclave with 5 atm of CO; soln. stirred for 5 h at 120 °C; removal of solvent under reduced pressure; products dissolved in pentaneand purified by column chromy. (neutral alumina, hexane); removal of so lvent in vacuo;
DOI:10.1021/om030429+