Pentafluorophenylmethylene-triphenyl-λ⁵-arsane

Base Information

• Chemical Name: Pentafluorophenylmethylene-triphenyl-λ⁵-arsane
• CAS No.: 109384-54-5
• Molecular Formula: C₂₅H₁₆AsF₅
• Molecular Weight: 486.316
• Mol file: 109384-54-5.mol

Synonyms:

Chemical Property of Pentafluorophenylmethylene-triphenyl-λ⁵-arsane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pentafluorophenylmethylene-triphenyl-λ⁵-arsane

There total 2 articles about Pentafluorophenylmethylene-triphenyl-λ⁵-arsane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triphenylmethylarsonium iodide (1499-33-8) → Pentafluorophenylmethylene-triphenyl-λ5-arsane (109384-54-5)

Guidance literature:

Multi-step reaction with 2 steps

1: phenyllithium / diethyl ether / 1 h / 20 °C

2: diethyl ether / 0.75 h / 0 - 20 °C

With phenyllithium; In diethyl ether;

DOI:10.1080/00397919108021289

Reference yield:

Hexafluorobenzene (392-56-3) + methylenetriphenylarsorane (47025-43-4,19365-61-8) → Pentafluorophenylmethylene-triphenyl-λ5-arsane (109384-54-5)

Guidance literature:

In diethyl ether; at 0 - 20 ℃; for 0.75h;

DOI:10.1080/00397919108021289

Reference yield:

isobutyl 2-bromoacetate (59956-48-8) + Pentafluorophenylmethylene-triphenyl-λ5-arsane (109384-54-5) → i-butyl 3-pentafluorophenyl acrylate (136436-77-6)

Guidance literature:

In diethyl ether; at 20 ℃; for 1h; Yield given;

DOI:10.1080/00397919108021289

upstream raw materials:

Hexafluorobenzene

methylenetriphenylarsorane

triphenylmethylarsonium iodide

Downstream raw materials:

i-butyl 3-pentafluorophenyl acrylate

(E)-n-butyl 3-(perfluorophenyl)acrylate

3-(pentafluorophenyl)-(E)-propenoic acid methyl ester

ethyl (E)-3-pentafluorophenylacrylate