{Ru₃(CO)11(P(C₆H₅)2H)}

Base Information

• Chemical Name: {Ru₃(CO)11(P(C₆H₅)2H)}
• CAS No.: 87984-98-3
• Molecular Formula: C₂₃H₁₁O₁₁PRu₃
• Molecular Weight: 797.517
• Mol file: 87984-98-3.mol

Synonyms:

Chemical Property of {Ru₃(CO)11(P(C₆H₅)2H)}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Ru₃(CO)11(P(C₆H₅)2H)}

There total 1 articles about {Ru₃(CO)11(P(C₆H₅)2H)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

benzophenone (119-61-9) + dodecacarbonyl-triangulo-triruthenium (15243-33-1) + diphenylphosphane (829-85-6) → {Ru3(CO)11(P(C6H5)2H)} (87984-98-3) + {Ru3(μ-H)(CO)10(μ-PPh2)}

Guidance literature:

In tetrahydrofuran; under N2, stirred for 40 min; chromy. on silica with 10 and 20% v/v CH2Cl2-light petroleum;

DOI:10.1039/DT9880002649

Reference yield: 85.0%

{Ru3(CO)11(P(C6H5)2H)} (87984-98-3) → {Ru3(μ-H)(CO)10(μ-PPh2)}

Guidance literature:

In n-heptane; A soln. of complex in heptane ws heated at 60°C for 10 h;; chromy. on Florisil with C7H16-C6H6, crystd. from heptane-benzene; elem. anal.;;

Reference yield:

{Ru3(CO)11(P(C6H5)2H)} (87984-98-3) → Ru3(μ3-PPh)(μ-H)2(CO)9

Guidance literature:

With H₂; In toluene; Ru-compd. heated in toluene at 80°C under N2, heated for further 2 h under H2; product sepn. by flash chromy.;

DOI:10.1039/DT9880002649

upstream raw materials:

benzophenone

dodecacarbonyl-triangulo-triruthenium

diphenylphosphane

Downstream raw materials:

[Pt₂Ru(CO)₂(μ-CO)₃(PPh₃)₃]

PtRu2(μ-PPh2)(μ-H)(CO)7(PPh3)

Pt₃(CO)3(PCy₃)3

PtRu2(μ-PPh2)(μ-H)(CO)7(PCy3)