(η5-C5H3-1,3-(SiMe3)2)2Ti=N-2,4,6-Me3C6H2

Base Information

Chemical Name:(η5-C5H3-1,3-(SiMe3)2)2Ti=N-2,4,6-Me3C6H2
CAS No.:728895-57-6
Molecular Formula:C₃₁H₅₃NSi₄Ti
Molecular Weight:599.991
Hs Code.:

Synonyms:

Suppliers and Price of (η5-C5H3-1,3-(SiMe3)2)2Ti=N-2,4,6-Me3C6H2

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (η5-C5H3-1,3-(SiMe3)2)2Ti=N-2,4,6-Me3C6H2

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (η5-C5H3-1,3-(SiMe3)2)2Ti=N-2,4,6-Me3C6H2

There total 1 articles about (η5-C5H3-1,3-(SiMe3)2)2Ti=N-2,4,6-Me3C6H2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 728895-52-1
((1,3-C₅H₃(SiMe₃)₂)₂Ti)₂(μ₂:η¹,η¹-N₂)

: 14213-00-4
2,4,6-trimethylaniline azide

: 728895-57-6
(η5-C5H3-1,3-(SiMe3)2)2Ti=N-2,4,6-Me3C6H2

Guidance literature:: In pentane; byproducts: N2; under N2; soln. of Ti complex in pentane chilled at -35°C for 20 min; MesN3 (2 equiv.) added to the warming soln.; warmed to ambient temp.; stirred for 20 min; filtered through glass frit; solvent removed from filtrate in vac.; recrystd. from pentane at -35°C; elem. anal.;
DOI:10.1021/om049817h

Reference yield:

: 728895-57-6
(η5-C5H3-1,3-(SiMe3)2)2Ti=N-2,4,6-Me3C6H2

: 1333-74-0
hydrogen

: 728895-65-6
(η5-C5H3-1,3-(SiMe3)2)2Ti(NH-2,4,6-Me3C6H2)H

Guidance literature:: In benzene-d6; in NMR tube; Ti complex in C6D6 degassed on high-vac. line; H2 (1 atm) admitted at -196°C; thawed; shaken; not isolated; detd. by (1)H and (13)C NMR spectra;
DOI:10.1021/om049817h

Reference yield:

: 728895-57-6
(η5-C5H3-1,3-(SiMe3)2)2Ti=N-2,4,6-Me3C6H2

: 16873-17-9,12184-84-8
deuterium

: (η5-C5H3-1,3-(SiMe3)2)2Ti(ND-2,4,6-Me3C6H2)D

Guidance literature:: In benzene-d6; byproducts: N2; in NMR tube; Ti complex in C6D6 degassed on high-vac. line; (2)H2 (1 atm) admitted at -196°C; thawed; shaken; not isolated; monitored by (1)H NMR spectra;
DOI:10.1021/om049817h