2,4-Dinitro-4'-methoxystilbene

Base Information

• Chemical Name: 2,4-Dinitro-4'-methoxystilbene
• CAS No.: 22396-03-8
• Molecular Formula: C15H12 N2 O5
• Molecular Weight: 300.271
• Hs Code.: 2909309090
• European Community (EC) Number: 653-959-8
• NSC Number: 406161
• DSSTox Substance ID: DTXSID80364314
• Nikkaji Number: J1.910.501F,J104.059F
• Wikidata: Q76139892
• Mol file: 22396-03-8.mol

Synonyms:2,4-Dinitro-4'-methoxystilbene;22396-03-8;1-[(E)-2-(4-methoxyphenyl)ethenyl]-2,4-dinitrobenzene;NSC406161;Anisole,4-dinitrostyryl)-;Oprea1_590378;SCHEMBL567172;1-[2-(4-Methoxy-phenyl)-vinyl]-2,4-dinitro-benzene;DTXSID80364314;Anisole, p-(2,4-dinitrostyryl)-;(E)-2,4-Dinitro-4'-methoxystilbene;AKOS000622772;NSC-406161;Z56871723;T0512-4748;4-[(E)-2-(2,4-dinitrophenyl)ethenyl]phenyl methyl ether

Chemical Property of 2,4-Dinitro-4'-methoxystilbene

Chemical Property:

• Vapor Pressure: 7.03E-08mmHg at 25°C
• Boiling Point: 450.4°C at 760 mmHg
• Flash Point: 193.1°C
• PSA: 100.87000
• Density: 1.362g/cm³
• LogP: 4.72840
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 3
• Exact Mass: 300.07462149
• Heavy Atom Count: 22
• Complexity: 421

Purity/Quality:

99% ^*data from raw suppliers

2,4-DINITRO-4PR-METHOXYSTILBENE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)C=CC2=C(C=C(C=C2)[N+](=O)[O-])[N+](=O)[O-]
• Isomeric SMILES: COC1=CC=C(C=C1)/C=C/C2=C(C=C(C=C2)[N+](=O)[O-])[N+](=O)[O-]

Technology Process of 2,4-Dinitro-4'-methoxystilbene

There total 2 articles about 2,4-Dinitro-4'-methoxystilbene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.8%

2,4-dinitrotoluene (121-14-2) + 4-methoxy-benzaldehyde (123-11-5) → 2,4-dinitro-4'-methoxystilbene (22396-03-8)

Guidance literature:

With pyrrolidine; at 90 ℃; for 0.5h;

DOI:10.1016/j.saa.2014.10.041

Reference yield: 50.0%

(2,4-dinitro-phenyl)-acetic acid (643-43-6) + 4-methoxy-benzaldehyde (123-11-5) → 2,4-dinitro-4'-methoxystilbene (22396-03-8)

Guidance literature:

With piperidine; at 100 - 130 ℃; for 8h;

DOI:10.1016/j.tet.2016.04.024

Reference yield: 15.0%

2,4-dinitro-4'-methoxystilbene (22396-03-8) → C15H16N2O

Guidance literature:

With sodium sulfide; sodium hydroxide; In ethanol; water; at 60 ℃;

DOI:10.1016/j.tet.2016.04.024

upstream raw materials:

2,4-dinitrotoluene

4-methoxy-benzaldehyde

(2,4-dinitro-phenyl)-acetic acid

Refernces

• 1、 Heying, Renata S.,Nandi, Leandro G.,Bortoluzzi, Adailton J.,Machado, Vanderlei G.. "A novel strategy for chromogenic chemosensors highly selective toward cyanide based on its reaction with 4-(2,4-dinitrobenzylideneamino)benzenes or 2,4-dinitrostilbenes". . p. 1491 - 1499. Retrieved 2015/02/19.