dichloro-nitrido-bis(triphenylphosphino)-rhenium(V)

Base Information

• Chemical Name: dichloro-nitrido-bis(triphenylphosphino)-rhenium(V)
• CAS No.: 412304-56-4
• Molecular Formula: C₃₆H₃₀Cl₂NP₂Re
• Molecular Weight: 795.701
• Mol file: 412304-56-4.mol

Synonyms:

Chemical Property of dichloro-nitrido-bis(triphenylphosphino)-rhenium(V)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloro-nitrido-bis(triphenylphosphino)-rhenium(V)

There total 10 articles about dichloro-nitrido-bis(triphenylphosphino)-rhenium(V) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

tetrabutylammonium tetrachloronitridorhenate(VI) + acetonitrile(trichloro)bis(triphenylphosphine)-rhenium(III) (16009-56-6,34387-57-0) → [ReNCl2(PPh3)2] (412304-56-4,25685-08-9)

Guidance literature:

In acetonitrile; to suspn. (ReCl3(PPh3)2(CH3CN)) in MeCN Me3SiNPPh3 was added and heated to reflux; elem. anal.;

DOI:10.1021/ic048210q

Reference yield: 90.0%

tetrabutylammonium tetrachloronitridorhenate(VI) + triphenylphosphine (603-35-0) → [ReNCl2(PPh3)2] (412304-56-4,25685-08-9)

Guidance literature:

In acetone; reflux (30 min); crystn. upon standing;

DOI:10.1039/a705881k

Reference yield: 85.0%

hydrogenchloride (7647-01-0,15364-23-5) + sodium azide + potassium perrhenate (10466-65-6) + triphenylphosphine (603-35-0) → trichlorooxobis(triphenylphosphine)rhenium(V) (34248-12-9) + [ReNCl2(PPh3)2] (412304-56-4,25685-08-9)

Guidance literature:

In water; acetone; KReO4 and aq. HCl refluxed for 30 min, aq. NaN3 added, mixt. refluxed for 30 min, soln. of P(C6H5)3 in acetone added, soln. refluxed for 30 min,longer refluxing time leads to oxotrichloro complex; ppt. collected by vac. filtration, washed with warm water, ethanol, and acetone;

DOI:10.1081/SIM-200047553

upstream raw materials:

hydrogenchloride

potassium perrhenate

triphenylphosphine

acetonitrile(trichloro)bis(triphenylphosphine)-rhenium(III)

Downstream raw materials:

Re(SC₆H₅)4(NP(C₆H₅)3)

[(bis[(diphenylphosphanyl)ethyl]methylamine)(N,N-(diethyl)dithiocarbamate)nitridorhenium(V)]Cl

trans-bis(isothiocyanato)(methoxy)(phenylimido)bis(triphenylphosphine)rhenium(V)

trans-hydroxotris(isothiocyanato)bis(triphenylphosphine)rhenium(IV) methanol solvate