1,3-bis(iodobis(triethylphosphine)platinum)phenylene

Base Information

• Chemical Name: 1,3-bis(iodobis(triethylphosphine)platinum)phenylene
• CAS No.: 405063-69-6
• Molecular Formula: C₃₀H₆₄I₂P₄Pt₂
• Molecular Weight: 1192.7
• Mol file: 405063-69-6.mol

Synonyms:

Chemical Property of 1,3-bis(iodobis(triethylphosphine)platinum)phenylene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 1,3-bis(iodobis(triethylphosphine)platinum)phenylene

There total 1 articles about 1,3-bis(iodobis(triethylphosphine)platinum)phenylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

tetrakis(triethylphosphine)platinum(0) (33937-26-7) + 1,3-Diiodobenzene (626-00-6) → 1,3-bis(iodobis(triethylphosphine)platinum)phenylene (405063-69-6)

Guidance literature:

In toluene; 85°C, 24 h, under N2; volatiles removed in vacuo at room temp., residue washed with hexane, filtd., recrystd. from hot hexane by cooling to -30°C overnight, dried for 12 h at 60°C; elem. anal.;

DOI:10.1039/b104579m

Reference yield: 72.0%

methanol (67-56-1) + silver(I) hexafluorophosphate (26042-63-7) + 1,3-bis(iodobis(triethylphosphine)platinum)phenylene (405063-69-6) + water (7732-18-5) + 4,4,5,5-tetramethylimidazoline-1-oxyl-2-p-pyridyl-3-oxide (38987-16-5) → [1,3-[Pt(PEt3)2(2-(4-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)]2C6H4][PF6]2*H2O*MeOH

Guidance literature:

In dichloromethane; AgPF6 was added to a CH2Cl2 soln. of Pt-complex under N2, after 30 min the reaction mixt. was filtd., filtrate combined with CH2Cl2 soln. of NITpPy and stirred for 12 h under N2; evapd. at room temp., washed with toluene, dissolved in CH2Cl2, filtd. through Celite, vapour diffusion of pentane yielded insoluble liquid which was dissolved in CH2Cl2, chromd. on SiO2 (CH2Cl2 followed by MeOH), recrystd. from MeOH; elem. anal.;

DOI:10.1039/b104579m

upstream raw materials:

tetrakis(triethylphosphine)platinum⁽⁰⁾

1,3-Diiodobenzene