chlorofluorenyldimesitylgermane

Base Information

Chemical Name:chlorofluorenyldimesitylgermane
CAS No.:1307801-51-9
Molecular Formula:C₃₁H₃₁ClGe
Molecular Weight:511.63
Hs Code.:

Synonyms:

Suppliers and Price of chlorofluorenyldimesitylgermane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of chlorofluorenyldimesitylgermane

Chemical Property:

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Technology Process of chlorofluorenyldimesitylgermane

There total 1 articles about chlorofluorenyldimesitylgermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 86-73-7
9H-fluorene

: 96481-42-4
dichlorodimesitylgermane

: 1307801-51-9
chlorofluorenyldimesitylgermane

Guidance literature:: With t-BuLi; In tetrahydrofuran; pentane; (Ar); Schlenk technique; soln. of BuLi in pentane was slowly added to soln. of fluorene in THF at -78°C; stirred for 1.5 h; soln. of Ge compd. in THF was slowly added; stirred at -78°C for 3 h; warmed to room temp.; stirred overnight; evapd. (vac.); hexane added; filtered; evapd. (vac.); recrystd. (hexane); elem. anal.;
DOI:10.1021/om200114n

Reference yield: 86.0%

: 14104-20-2
silver tetrafluoroborate

: 1307801-51-9
chlorofluorenyldimesitylgermane

: 108920-25-8
fluorobis(2,4,6-trimethylphenyl)fluorenylgermane

Guidance literature:: In dichloromethane; (Ar); Schlenk technique; Ag salt was added to soln. of Ge compd. in CH2Cl2; stirred at room temp. for 1 h; decanted; solvent removed (vac.); thin layer chromd. (SiO2, CHCl3);
DOI:10.1021/om200114n

Reference yield:

: 1307801-51-9
chlorofluorenyldimesitylgermane

: C₃₅H₃₈GeO₂

Guidance literature:: Multi-step reaction with 4 steps

1.1: Inert atmosphere

2.1: Inert atmosphere

3.1: tert.-butyl lithium / diethyl ether; pentane / 2 h / -78 - 20 °C / Inert atmosphere

4.1: water / tetrahydrofuran / Inert atmosphere

4.2: Inert atmosphere

With water; tert.-butyl lithium; In tetrahydrofuran; diethyl ether; pentane; 4.1: |Diels-Alder Cycloaddition;
DOI:10.1139/cjc-2013-0532