3-Butenoic acid, 2-[[(1,1-diMethylethoxy)carbonyl]aMino]-, Methyl ester, (2S)-

Base Information

Chemical Name:3-Butenoic acid, 2-[[(1,1-diMethylethoxy)carbonyl]aMino]-, Methyl ester, (2S)-
CAS No.:852693-74-4
Molecular Formula:C₁₀H₁₇NO₄
Molecular Weight:215.249
Hs Code.:
Mol file:852693-74-4.mol

Synonyms:

Suppliers and Price of 3-Butenoic acid, 2-[[(1,1-diMethylethoxy)carbonyl]aMino]-, Methyl ester, (2S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
(S)-2-TERT-BUTOXYCARBONYLAMINO-BUT-3-ENOIC ACID METHYL ESTER 95.00%
5MG
$ 501.77

Total 4 raw suppliers

Chemical Property of 3-Butenoic acid, 2-[[(1,1-diMethylethoxy)carbonyl]aMino]-, Methyl ester, (2S)-

Chemical Property:

Vapor Pressure:0.00093mmHg at 25°C
Boiling Point:303.4±35.0 °C(Predicted)
PKA:10.70±0.46(Predicted)
Density:1.050±0.06 g/cm3(Predicted)

Purity/Quality:

98%+ ^*data from raw suppliers

(S)-2-TERT-BUTOXYCARBONYLAMINO-BUT-3-ENOIC ACID METHYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-Butenoic acid, 2-[[(1,1-diMethylethoxy)carbonyl]aMino]-, Methyl ester, (2S)-

There total 17 articles about 3-Butenoic acid, 2-[[(1,1-diMethylethoxy)carbonyl]aMino]-, Methyl ester, (2S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 63658-16-2
(Z)-methyl 2-((tertbutoxycarbonyl)amino)but-2-enoate

: 100038-68-4,852693-74-4
2-tert-Butoxycarbonylamino-but-3-enoic acid methyl ester

Guidance literature:: With dibromo(dimethylglyoxime)(dimethylglyoximato)cobalt(III); sodium decatungstate; 1,2-bis(2,4,6-triisopropylphenyl)disulfane; In acetone; at 20 ℃; for 18h; regiospecific reaction; Irradiation; Inert atmosphere; Sealed tube;
DOI:10.1021/jacs.1c12043

Reference yield: 20.0%

: 1826-67-1
vinyl magnesium bromide

: 138219-39-3
2-bromo-2-(N-tert-butoxycarbonylamino)acetic acid methyl ester

: 100038-68-4,852693-74-4
2-tert-Butoxycarbonylamino-but-3-enoic acid methyl ester

Guidance literature:: In tetrahydrofuran; at -78 ℃; for 2h;

Reference yield:

: 31954-27-5
N-(tert-butoxycarbonyl)glycine methyl ester

: 100038-68-4,852693-74-4
2-tert-Butoxycarbonylamino-but-3-enoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 99 percent / NBS / dimethylsulfoxide / 1 h / 10 - 30 °C / Irradiation

2: 20 percent / tetrahydrofuran / 2 h / -78 °C

With N-Bromosuccinimide; In tetrahydrofuran; dimethyl sulfoxide;