3-(tert-Butyldimethylsilanyloxy)-2-methylpropyl-4-methylbenzenesulfonate

Base Information

Chemical Name:3-(tert-Butyldimethylsilanyloxy)-2-methylpropyl-4-methylbenzenesulfonate
CAS No.:885266-52-4
Molecular Formula:C₁₇H₃₀O₄SSi
Molecular Weight:358.574
Hs Code.:
DSSTox Substance ID:DTXSID401119232
Mol file:885266-52-4.mol

Synonyms:DTXSID401119232;FT-0664087;3-(tert-Butyldimethylsilanyloxy)-2-methylpropyl-4-methylbenzenesulfonate;1-Propanol, 3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-methyl-, 1-(4-methylbenzenesulfonate);885266-52-4

Suppliers and Price of 3-(tert-Butyldimethylsilanyloxy)-2-methylpropyl-4-methylbenzenesulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 3-(tert-Butyldimethylsilanyloxy)-2-methylpropyl-4-methylbenzenesulfonate

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:8
Exact Mass:358.16340714
Heavy Atom Count:23
Complexity:454

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)OCC(C)CO[Si](C)(C)C(C)(C)C

Technology Process of 3-(tert-Butyldimethylsilanyloxy)-2-methylpropyl-4-methylbenzenesulfonate

There total 8 articles about 3-(tert-Butyldimethylsilanyloxy)-2-methylpropyl-4-methylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 112057-64-4
(R)-3-(tert-butyldimethylsilyloxy)-2-methylpropan-1-ol

: 98-59-9
p-toluenesulfonyl chloride

: 222539-29-9,885266-52-4
(2S)-toluene-4-sulfonic acid 3-(tert-butyldimethylsilanyloxy)-2-methylpropyl ester

Guidance literature:: In pyridine; at 0 ℃; for 12h;
DOI:10.1002/1099-0690(200008)2000:15<2745::AID-EJOC2745>3.0.CO;2-I

Reference yield: 100.0%

: 105859-45-8
(S)-3-(tert-butyldimethylsilyloxy)-2-methylpropan-1-ol

: 98-59-9
p-toluenesulfonyl chloride

: 299430-30-1,885266-52-4
(2R)-toluene-4-sulfonic acid 3-(tert-butyldimethylsilanyloxy)-2-methylpropyl ester

Guidance literature:: In pyridine; at 0 ℃; for 12h;
DOI:10.1002/1099-0690(200008)2000:15<2745::AID-EJOC2745>3.0.CO;2-I

Reference yield:

: 93454-85-4
(S)-3-(tert-butyldimethylsilyloxy)-2-methylpropionic acid methyl ester

: 222539-29-9,885266-52-4
(2S)-toluene-4-sulfonic acid 3-(tert-butyldimethylsilanyloxy)-2-methylpropyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / CH₂Cl₂; hexane / -40 - 20 °C

2: 92 percent / DMAP / CH₂Cl₂ / 16 h / 20 °C

With dmap; In hexane; dichloromethane;
DOI:10.1021/jo051526a