(E)-3-Chlorostilbene

Base Information

• Chemical Name: (E)-3-Chlorostilbene
• CAS No.: 14064-43-8
• Molecular Formula: C14H11Cl
• Molecular Weight: 214.694
• Mol file: 14064-43-8.mol

Synonyms:(E)-1-chloro-3-styrylbenzene;3-Chlor-trans-stilben;Benzene, 1-chloro-3-(2-phenylethenyl)-, (E)-;1-Chloro-3-((E)-styryl)-benzene;trans-3-chlorostilbene;1-chloro-3-[(E)-2-phenylethenyl]benzene;(E)-1-chloro-3-(2-phenylethenyl)-benzene;3-chloro-trans-stilbene;

Chemical Property of (E)-3-Chlorostilbene

Chemical Property:

• Melting Point: 73.5°C
• Refractive Index: 1.6012 (estimate)
• Boiling Point: 175 - 180 °C (0.2 mmHg)
• PSA: 0.00000
• Density: 1.1475 (rough estimate)
• LogP: 4.51040

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (E)-3-Chlorostilbene

There total 55 articles about (E)-3-Chlorostilbene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 1-bromo-3-chlorobenzene (108-37-2) → (E)-3-chlorostilbene (14064-43-8)

Guidance literature:

With potassium carbonate; In methanol; water; at 45 ℃; for 6h; stereoselective reaction; Catalytic behavior; Green chemistry;

DOI:10.1016/j.molstruc.2014.01.071

Reference yield: 95.0%

1-phenyl-1-chloro-2-(3-chlorophenyl)ethane (146736-38-1) → (E)-3-chlorostilbene (14064-43-8)

Guidance literature:

With potassium hydroxide; In ethanol; for 0.333333h; Heating;

Reference yield: 94.0%

1-chloro-3-(2-phenylethynyl)benzene (51624-34-1) → (E)-3-chlorostilbene (14064-43-8)

Guidance literature:

With methanol; borane-ammonia complex; C₁₆H₂₉Cl₂CoN₂P; at 50 ℃; for 16h; chemoselective reaction; Inert atmosphere; Schlenk technique;

DOI:10.1021/jacs.6b04271

upstream raw materials:

3-chloro-aniline

benzyl bromide

m-Chlorobenzaldehyde

(Z)-1-chloro-3-styrylbenzene

Downstream raw materials:

trans-2-(m-chlorophenyl)-3-phenyloxirane

3-chloro-bibenzyl

1-((E)-styryl)-3-((E)-4-(trifluoromethyl)styryl)benzene

(E)-3-styrylbiphenyl