[Fe(C_.tplbond.CPh)2(P(OEt)3)4]

Base Information

Chemical Name:[Fe(C_.tplbond.CPh)2(P(OEt)3)4]
CAS No.:167383-71-3
Molecular Formula:C₄₀H₇₀FeO₁₂P₄
Molecular Weight:922.731
Hs Code.:

[Fe(C<sub>.</sub>tplbond.CPh)2(P(OEt)3)4]

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Fe(C_.tplbond.CPh)2(P(OEt)3)4]

Chemical Property:

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Technology Process of [Fe(C_.tplbond.CPh)2(P(OEt)3)4]

There total 1 articles about [Fe(C_.tplbond.CPh)2(P(OEt)3)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

: 7439-93-2
lithium

: 536-74-3
phenylacetylene

: iron(II) chloride

: 122-52-1
triethyl phosphite

: 167383-71-3
[Fe(C_.tplbond.CPh)2(P(OEt)3)4]

Guidance literature:: In tetrahydrofuran; Ar-atmosphere; stirring of FeCl2 with excess of phosphite (2 h), addn. of 2 equiv. alkyne salt (prepd. from alkyne and Li in THF), addn. of THF, stirring (1 h); solvent removal (reduced pressure), dissoln. of oil in THF, chromy. (SiO2, hexane/THF=4:1), evapn. to dryness, treatment of oil with MeOH, filtration, drying (vac.); elem. anal.;
DOI:10.1039/DT9950001783

Reference yield:

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 167383-71-3
[Fe(C_.tplbond.CPh)2(P(OEt)3)4]

: 167383-76-8
[Fe(C_.tplbond.CPh)(=C=CHPh)(P(OEt)3)4]BF₄

Guidance literature:: In diethyl ether; Ar-atmosphere; addn. of slight excess of HBF4 to Fe-complex (-80°C), slow warming to room temp., stirring (30 min, pptn.); filtration, drying (vac.); elem. anal.;
DOI:10.1039/DT9950001783

Reference yield:

: 167383-71-3
[Fe(C_.tplbond.CPh)2(P(OEt)3)4]

: 333-27-7
methyl trifluoromethanesulfonate

: 167383-82-6
[Fe(C_.tplbond.CPh)(=C=C(Me)Ph)(P(OEt)3)4]CF₃SO₃

Guidance literature:: In diethyl ether; Ar-atmosphere; addn. of slight excess of CF3SO3Me to Fe-complex (-80°C), slow warming to room temp., stirring (20-30 min, pptn.); filtration, drying (vac.); elem. anal.;
DOI:10.1039/DT9950001783